chem chapter 8 Flashcards

1
Q

valance electrons of an atom for main group elements

A

s and p electrons with highest value of n
ex: carbon: 1s2 2s2 2p2, valence =2s2 2p2=4 (counting the exponents)
the core electrons are the ones not included

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2
Q

valance electrons for transition metals

A

s and d electrons with the highest value of n
ex) Titanium: [Ar] 4s2 3d2, valance =4
the core electrons are the ones not included

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3
Q

chemical reactions with core and valance electrons

A

-core: not participating in the chemical reaction or bonds (ignore them)
-valance electrons: chemical reactions result in the loss, gain, or rearrangement of valance electrons

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4
Q

atoms tend to ionize until they achieve…

A

the valance electron configuration of a noble gas (ns2 np6)
they will bond to achieve this

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5
Q

covalent compound

A

nonmetal + nonmetal
electrons SHARED through bonds

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6
Q

ionic compound

A

metal + nonmetal
electrons are TRANSFERRED and electrostatic forces keep the ions together

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7
Q

octet rule

A

atoms want to have 8 valance electrons and will bond to get there

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8
Q

lewis symbols of ions

A

have either 8 valance electrons or none

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9
Q

cations with lewis symbols

A

take away the electrons to make a positive charge

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10
Q

anions with lewis symbols

A

add electrons to equal a negative charge

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11
Q

when does a chemical reaction occur?

A

when two atoms have some of their valance electrons reorganized resulting in a net attractive force between the atoms (a chemical bond)

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12
Q

bonding pair

A

the SHARED electrons in covalent compounds

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13
Q

pure covalent compound

A

occurs when two identical atoms are bonded
ex) H + H goes to H2

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14
Q

what happens when two different atoms form a covalent compound?

A

the electrons are shared unequally
the bonding electrons will be closer to the more electronegative atom

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15
Q

polar covalent bond

A

bonding of two different atoms in a covalent compound
one atom has a partial negative charge and the other has a partial negative charge
(because the electrons will move to the more electronegative atom)

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16
Q

the greater the difference in electronegativity in two atoms…

A

the more polar the bond

17
Q

metallic bond

A

metal + metal
when metals form a lattice and a sea of delocalized electrons are spread through the lattice

18
Q

no or very little difference in EN=

A

covalent

19
Q

moderate difference in EN=

A

polar covalent

20
Q

large difference in EN=

A

ionic

21
Q

can chemical bonds always be categorized as either ionic, metallic, or covalent?

A

no, chemical bonds exhibit characteristics of all three kinds of bonding

22
Q

do ionic compounds form molecules?

A

no, they form lattice/crystal structures

23
Q

lattice energy

A

indicates how strongly ions are attracted to each other in the solid state

24
Q

when does lattice energy increase? What is the trend?

A

it increases with increasing ionic charge and decreasing ionic size
it wants a large charge or a small size!