Chapter Six: Electronic Structure Flashcards

1
Q

What is this?
- the arrangement and energy of electrons in atoms

A

Electronic Structure

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2
Q

Materials that glow give off light and that light possesses a broad range (______________) of colors

A

spectrum

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3
Q

Energy comes in packets called…

A

quanta

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4
Q

What is the 3-step explanation of discrete (line) spectra results that was created by Planck, Bohr, and Einstein?

A
  1. Electrons in an atom can only occupy certain orbits
  2. Energy is only absorbed or emitted to move an electron from an one energy state to another
  3. The atoms absorb or radiate light to make the energy jump from one orbital to another
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5
Q

∆E electron = ∆E light =….

A

hv

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6
Q

What is planks constant?

A

6.626 x 10^-34

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7
Q

When an electron moves closer to the nucleus it radiates ___________. The smallest package of light energy is the photon.

A

light

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8
Q

Bohr model has values called “__”. they are Bohr orbitals

A

n

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9
Q

(+∆E) means energy is ___________. A photon is absorbed in this instance
N final > N initial

A

absorbed

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10
Q

(-∆E) means energy is _____________. A photon is emitted in this instance.
N final < N initial

A

Released

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11
Q

What is this?
The energy level an electron ordinarily occupies when nonexcited

A

Ground State

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12
Q

What are the two limitations of the Bohr Atomic Model?

A
  1. works best for Hydrogen, but meh for others
  2. With the circular orbit model, electrons would constantly be crashing into the nucleus
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13
Q

Wavelength measures…

A

peak to peak

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14
Q

frequency measures….

A

the # of waves passing a given observation point per unit of time

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15
Q

Speed of traveling wave is what times what?

A

wavelength times frequency

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16
Q

All forms of ________________ _______________ travels through space at the same speed

A

Electromagnetic Reaction

17
Q

What type of Ultraviolet Rays?
100-280

A

UVC

18
Q

What type of Ultraviolet Rays?
280-315

A

UVB

19
Q

What type of Ultraviolet Rays?
315-400

A

UVA

20
Q

What kind of effect?
Metals hold electrons but not infinitely tight. If one of the electrons absorbs a photon with enough energy, it can break free from the metal; any leftover energy after that becomes kinetic energy of the electron

A

Photoelectric Effect

21
Q

The farther the shell from the nucleus, the _____________ the energy

A

greater

22
Q

Is Shell 3 or Shell 1 more desirable?

A

Shell 1

23
Q

Principle Quantum Number (n)
- The principle quantum #, n, describes the _______ _________ in which the orbital resides
- the values of n are integers >= 1

A

energy shell

24
Q

We can only put ____ electrons in any actual orbital

A

2

25
Q

Angular Momentum Quantum # (l)
- the quantum number defines the _________ of the orbital
- allowed values of l are integers ranging from 0 to (n-1)
- the number associated with l defines the shape of the orbitals

A

shape

26
Q

if the value of l is 0, what is the shape letter?

A

s

27
Q

If the value of l is 1, what is the shape letter?

A

p

28
Q

If the value of l is 2, what is the shape letter?

A

d

29
Q

Magnetic Quantum # (ml)
- the magnetic quantum # describes the __________ - ____________ orientation of the orbital
- allowed values are integers ranging from -1 to 1

A

three-dimensional

30
Q

The way electrons are distributed in an atom is called its….

A

electron configuration

31
Q

Each statement of a configuration consists of what two things?

A
  1. a number denoting the type of orbital (subshell)
  2. a superscript denoting the number of electrons in those orbitals
32
Q

Who’s rule?
- for a set of orbitals in the same subshell, there must be (a) one electron in each orbital before pairing and (b) those electrons have the same spin, as much as possible

A

Hund’s Rule

33
Q

The spin of an electron describes its ______________ _____________, which affects its energy

A

magnetic field

34
Q

The spin quantum number (ms) has only two allowed values, what and what?

A

+1/2 and -1/2