Chapter 7.1 Flashcards

1
Q

What is the system

A
  • it is the matter that is being observed

- >the total amount of reactants and products in a chemical reaction

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2
Q

What is the environment

A

-it is everything outside the system

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3
Q

Describe isolated system, closed system and open system

A

Isolated

  • > system cannot exchange energy(heat and work)
  • > or matter with the surroundings

Closed

  • > the system can exchange energy(heat and work)
  • > but not matter

Open
->the system can exchange both energy(heat and work) and matter with the surroundings

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4
Q

What is a process in terms of the system

A
  • when a system experiences change in one or more of its properties
  • > it undergoes a process
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5
Q

What are isothermic processes? What does this indicate about the equation regarding the first law of thermodynamics

A
  • system’s temperature is constant
  • > constant temperature implies that the total internal energy of the system is constant
  • > this is because internal energy and temperature are directly proportional

-therefore, change in internal energy(U) is zero and at this point Q=W

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6
Q

What are adiabatic processes? What does this indicate about the equation regarding the first law of thermodynamics?

A
  • no heat is exchanged between the system and the surroundings
  • > thus the thermal energy of the system is constant throughout the process
  • > therefore, Q=0
  • > the first law simplifies to change in U= -W
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7
Q

Do isobaric processes alter the equation for the first law of thermodynamics

A

-no it doesn’t alter the first law of thermodynamics

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