Chapter 7: Quantum Theory and the Electronic Structure of Atoms Flashcards

1
Q

Actinide Series

A

Elements that have incompletely filled 5f subshells or readily give rise to cations that have incompletely filled 5f subshells

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2
Q

Amplitude

A

The vertical difference from the middle of a wave to the peak or trough

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3
Q

Atomic Orbital

A

The wave function (psi) of an electron in an atom

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4
Q

Aufbau principle

A

As protons are added one by one to the nucleus to build up the elements, electrons similarly are added to the atomic orbitals

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5
Q

Boundary surface diagram

A

Diagram of the region containing a substantial amount of the electron density (about 90%) in an orbital

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6
Q

Dimagnetic

A

Repelled by a magnet, a dimagnetic substance contains only paired electrons

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7
Q

Electromagnetic radiation

A

The emission and transmission of energy in the form of electromagnetic waves

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8
Q

Electromagnetic wave

A

A wave that has an electric field component and a mutually perpendicular magnetic field component

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9
Q

Electron configuration

A

The distribution of electrons among the various orbitals in an atom or molecule

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10
Q

Electron density

A

The probability that an electron will be found at a particular region in an atomic orbital

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11
Q

Emission spectra

A

Continuous or line spectra emitted by substances

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12
Q

Excited level/state

A

A state that has higher energy than the ground state

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13
Q

Frequency

A

(nu) the number of waves that pass through a particular point per unit time

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14
Q

Ground level

A

The lowest energy state of a system

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15
Q

Ground state

A

The lowest energy state of a system

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16
Q

Heisenberg uncertainty principle

A

It is impossible to know simultaneously both the momentum and the position of a particle with certainty

17
Q

Hund’s Rule

A

The most stable arrangement of electrons in subshells is the one with the greatest number of parallel spins

18
Q

Lanthanide

A

Elements that have incompletely filled 4f subshells or readily give rise to cations that have incompletely filled 4f subshells

19
Q

Line spectra

A

Spectra produced when radiation is absorbed or emitted by substances only at some wavelengths

20
Q

Many-electron atom

A

Atoms that contain two or more electrons

21
Q

noble gas core

A

The electron configuration of the noble gas element that most nearly precedes the element being considered

22
Q

node

A

The point at which the amplitude of the wave is zero

23
Q

paramagnetic

A

Attracted by a magnet. A paramagnetic substance contains one ore more unpaired electros

24
Q

Pauli exclusion principle

A

No two electrons in an atom can have the same four quantum numbers

25
Q

Photoelectric effect

A

A phenomenon in which electrons are ejected from the surface of certain metals exposed to light of at least a certain minimum frequency

26
Q

Photon

A

A particle of light

27
Q

Quantum

A

The smallest quantity of energy that can be emitted (or absorbed) in the form of electromagnetic radiation.

28
Q

Quantum numbers

A

Numbers that describe the distribution of electrons in hydrogen and other atoms

29
Q

Rare earth series

A

Same as lanthanide series

30
Q

Transition metals

A

Elements that have incompletely filled d subshells or readily give rise to cations that have incompletely filled d subshells

31
Q

Wave

A

A vibrating disturbance by which energy is transmitted

32
Q

Wavelength

A

(lambda) The distance between identical points on successful waves