Chapter 7 Flashcards

1
Q

Boiling point

A

The temp at which the vapor pressure of a liquid equals the pressure exerted on liquid by its surroundings

Water boiling point is 100°C b/c this is the temp at which the vapor pressure of water is 760mmHg or 1 atm

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2
Q

🔺H°(vap)

A

Molar enthalpy of vaporization

The heat required to convert one mole of liquid to a gas at its normal boiling point

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3
Q

🔺H°(fus)

A

Molar enthalpy of fusion

The heat required to convert one mole of a solid to a liquid at its normal melting point

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4
Q

Solid to liquid

A

Melting

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5
Q

Liquid to solid

A

Freezing

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6
Q

Liquid to gas

A

Vaporization

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7
Q

Gas to liquid

A

Condensation

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8
Q

Solid to gas

A

Sublimation

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9
Q

Gas to solid

A

Deposition

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10
Q

Intermolecular forces

A

Attractive forces between molecules or atoms or ions

Hold DNA molecules in a helix and are the mechanism for DNA transcription

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11
Q

Electronegativity

A

The tendency of an atom in a molecule to attract shared electrons to itself

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12
Q

Dipole-Dipole Attraction

A

The attraction between the opposite (partial) charges of polar molecules

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13
Q

London forces

A
Some non-polar molecules induce dipole bonding 
Also called Van der Waal’s forces
Created by instantaneous dipoles
Much weaker
Get stronger with larger atoms/molecules
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14
Q

Hydrogen bonding

A

Stronger than Dipole

The attraction b/w a hydrogen bonded directly to an O, N, or F & another electronegative atom

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15
Q

Surface tension

A

Asymmetrical forces acting at an air/water interface produce a net force acting to decrease surface area

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16
Q

Vapor pressure

A

The pressure exerted by molecules once they are free as gases

17
Q

Saturated vapor pressure

A

The pressure at which the gaseous state is in equilibrium with either the liquid state, solid state or both

At boiling point, the SVP = atmospheric pressure