Chapter 5 - The Periodic Law Flashcards

1
Q

What is the name for repeating patterns?

A

Periodic

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2
Q

What is the periodic law?

A

The physical and chemical properties of the elements are periodic functions of their atomic numbers

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3
Q

How is the modern periodic table arranged?

A

In order of atomic number so that elements with similar properties fall in the same group

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4
Q

Group 1

  • name
  • outer electron shell description
  • appearance
  • reactivity
  • exception
A
Alkali
1 electron in outer s orbital
Silvery appearance and soft
Very reactive
Does not include hydrogen
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5
Q

Group 2

  • name
  • outer shell description
  • reactivity
A

Alkaline-Earth
2 electrons in outer s shell
Less reactive than alkali, but still too reactive to be found pure in nature

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6
Q

What group number and type of electron shell does helium have?

A

Group 18 with two valence electrons in its filled outer shell, which gives it special chemical stability

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7
Q

What type of elements are in the d block?

A

Transition

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8
Q

What are the elements called in the s and p blocks?

A

Main-group

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9
Q

What three types fill the p block?

A

Non-metals, metals, metalliods

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10
Q

What are the group 17 elements called, how reactive are they, and what do they form when they do react?

A

Halogens, most reactive of all of the nonmetals, form salts

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11
Q

Where are the Metalliods?

A

Stair-step between nonmetals and metals

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12
Q

What is the first row under the periodic table called and what group can they be compared to in reactivity?

A

Lanthanides, group 2

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13
Q

What is the second row under the periodic table called and what is their special characteristic?

A

Actinides, all radioactive

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14
Q

Who made the very first periodic table and how was it arranged?

A

Mendeleev- by average atomic mass

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15
Q

How did Mendeleev know that his table was well-designed?

A

He predicted three elements that were discovered later (all before 1886). Ekaaluminum was Gallium, Ekaboron was Scandium and Ekasilicon was Germanium. He was able to predict many of their properties before they were discovered.

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16
Q

Who changed the first periodic table and how did he change it?

A

Mosely discovered that the elements fit better when arranged according to atomic number

17
Q

What is the definition of the modern periodic table?

A

An arrangement of the elements in order of their atomic number so that elements with similar properties fall in the same column, or group

18
Q

What are the differences in atomic number in a group? (group 18)

A

He-Ne-Ar-Kr-Xe-Rn is 8-8-18-18-32 (they represent the different sublevels that are being filled 8=sp 18=spd 32=spdf)

19
Q

What are the general properties, name, and reactivity of the d-block elements?

A

Metallic properties, transition elements, low reactivity

20
Q

What is group 18 called and how reactive are they?

A

Noble-gases, not reactive

21
Q

How is the length of the period determined?

A

The number of electrons that can occupy the sublevels being filled in that period

22
Q

What are the four blocks of the periodic table?

A

S, P, D, and F (they are determined by the sublevel being filled

23
Q

What is the definition of atomic radius?

A

One-half the distance between the nuclei of identical atoms that are bonded together

24
Q

What are the trends of the atomic radius in the periodic table + explain?

A

They increase as you go left and down
The size of the nucleus shrinks as you go right because more protons are being added which attracts the electrons (Zee effective charge) and they grow as you go down the table because the electron cloud is growing as sublevels are added

25
Q

What is an ion?

A

An atom of group of bonded atoms that has a positive or negative charge

26
Q

What is ionization energy (or first ionization energy)?

A

The energy required to remove one electron from a neutral atom of an element

27
Q

What are the trends of ionization energy in the periodic table + explain?

A

They increase as you go right and up
The ionization energy increases as you go right because more protons are being added which attracts the electrons (Zee effective charge) and they grow as you go up the table because the electron cloud is shrinking as sublevels are removed (bigger cloud = easier to remove)

28
Q

What is electron affinity?

A

The energy change that occurs when an electron is acquired by a neutral atom

29
Q

What are the trends of electron affinity in the periodic table + explain?

A

They increase as you go right and up
The electron affinity increases as you go right because more protons are being added which attracts the electrons (Zee effective charge) and they grow as you go up the table because the electron cloud is shrinking as sublevels are removed (bigger cloud = easier to remove)

30
Q

What is a cation?

A

A positive ion formed by the loss of one or more electrons

31
Q

How does the formation of a cation change the atom (size) and why?

A

The atom (radius) shrinks; the remaining electrons are attracted more by the unbalanced positive charge

32
Q

What is a anion?

A

A negative ion formed by the addition of one or more electrons

33
Q

How does the formation of a anion change the atom (size) and why?

A

The atom (radius) grows; the greater electron repulsion causes the electrons to spread out more

34
Q

What are the trends of ionic radius in the periodic table + explain?

A

They increase as you go left and down
The size of the nucleus shrinks as you go right because more protons are being added which attracts the electrons (Zee effective charge) and they grow as you go down the table because the electron cloud is growing as sublevels are added

35
Q

What are valence electrons?

A

The electrons available to be lost, gained, or shared in the formation of chemical compounds

36
Q

What is electronegativity?

A

A measure of the ability of an atom in a chemical compound to attract electrons from another atom in the compound

37
Q

What are the trends of electronegativity in the periodic table?

A

They tend to increase across periods and decrease or remain the same down a group