Chapter 5, Carbonyl Groups (Carboxylic Acids and Esters) Flashcards
What is a carboxylic acid?
A weak acid that can liberate C02 from carbonates
They have all the typical reactions with metals to produce salt+water
Higher the Ka value…
…the greater the dissociation of the acid adn the greater the strength
Carboxylic acid reacts with___ in the presence of ___ to produce___
Alcohols
A strong acid catalyst
An ester
The distinctive property of an ester is?
It is sweet smelling
Methylethanoate is produced from?
Methanol + Ethanoic Acid
What is an example of a strong acid catalyst?
H2SO4
What are the uses of esters?
Solvents, Plasticisers, Perfumes, Food Flavourings
What are the 2 types of hydrolysis or esters?
Acid hydrolysis
Alkaline hydrolysis
What does acid hydrolysis produce?
The acid + the alcohol
What does alkaline hydrolysis produce?
Salt of the acid + the alcohol
E.G acid hydrolysis of ethylmethanoate…
CH2COOH + H2O= HCOOH + C2H5OH
What are esters formed from glycerol and fatty acids called?
Triglycerides
What are triglyceride’s formed from?
Fatty acids and glycerol
What are triglyceride hydrolysed by?
NaOH
What are the key properties of glycerol?
It has 3 O-H groups
therefore has a high affinity for water
Exhibits extensive hydrogen bonding