Chapter 5 Flashcards

1
Q

atmosphere

A

the mixture of gases that extends from a planet’s surface and eventually merges with outer space; the gaseous region of Earth’s crust

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2
Q

Avogadro’s law

A

the gas law stating that, at fixed temperature and pressure, equal volumes of any ideal gas contain equal numbers of particles, and, therefore, the volume of a gas is directly proportional to its amount (mol): V ∝ n

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3
Q

barometer

A

a device used to measure atmospheric pressure. most commonly, a tube open at one end, which is filled with mercury and inverted into a dish of mercury

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4
Q

Boyle’s law

A

the gas law stating that, at constant temperature and amount of gas, the volume occupied by a gas is inversely proportional to the applied (external) pressure: V ∝ 1/P

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5
Q

Charles’ law

A

the gas law stating that, at constant pressure, the volume occupied by a fixed amount of gas is directly proportional to its absolute temperature: V ∝ T

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6
Q

collision frequency

A

the average number of collisions per second that a particle undergoes

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7
Q

Dalton’s law of partial pressures

A

a gas law stating that, in a mixture of unreacting gases, the total pressure is the sum of the partial pressures of the individual gases: Ptotal = P1 + P2 + P3 + ….

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8
Q

diffusion

A

the movement of one fluid through another

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9
Q

effusion

A

the process by which a gas escapes from its container through a tiny hole into an evacuated space

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10
Q

Graham’s law of effusion

A

a gas law stating that the rate of effusion of a gas is inversely proportional to the square root of its density (or molar mass): rate = 1/sqrt MM

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11
Q

ideal gas

A

a hypothetical gas that exhibits linear relationships among volume, pressure, temperature, and amount (mol) at all conditions; approximated by simple gases at ordinary conditions

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12
Q

ideal gas law

A

an equation that expresses the relationships among volume, pressure, temperature, and amount (mol) of an ideal gas: PV = nRT

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13
Q

kinetic molecular theory

A

the model that explains macroscopic gas behavior in terms of particles in random motion whose volumes and interactions are negligible

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14
Q

manometer

A

a device used to measure the pressure of a gas in a laboratory experimen

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15
Q

mean free path

A

the average distance a particle travels between collisions at a given temperature and pressure

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16
Q

millimeter of mercury mmHg

A

a unit of pressure based on the difference in the heights of mercury in a barometer or manometer. renamed the torr in honor of Torricelli

17
Q

mole fraction (X)

A

a concentration term expressed as the ratio of number of moles of solute to the total number of moles (solute plus solvent)

18
Q

partial pressure

A

the portion of the total pressure contributed by a gas in a mixture of gases

19
Q

pascal (Pa)

A

the SI unit of pressure; 1 Pa = 1 N/m2

20
Q

pressure (P)

A

the force exerted per unit of surface area

21
Q

rms speed

A

the speed of a molecule having the average kinetic energy; very close to the most probable speed

22
Q

standard atmosphere (atm)

A

the average atmospheric pressure measured at sea level and 0°C, defined as 1.01325 × 105 Pa

23
Q

standard molar volume

A

the volume of 1 mol of an ideal gas at standard temperature and pressure: 22.4141 L

24
Q

standard temperature and pressure (STP)

A

the reference conditions for a gas: 0°C (273.15 K) and 1 atm (760 torr)

25
Q

torr

A

a unit of pressure identical to 1 mmHg

26
Q

universal gas constant (R)

A

a proportionality constant that relates the energy, amount of substance, and temperature of a system; R = 0.0820578 atm·L/mol·K = 8.31447 J/mol·K

27
Q

van der Waals constants

A

experimentally determined positive numbers used in the van der Waals equation to account for the interparticle attractions and particle volume of real gases

28
Q

van der Waals equation

A

an equation that accounts for the behavior of real gases