Chapter 4 Flashcards
Organic chemistry
study of compounds that contain carbon
Carbon importance
-4 valence electrons so it can form 4 covalent bonds with variety of atoms
-ability makes large, complex molecules possible
-carbon chains form skeletons of most organic molecules that vary in length and shape
Hydrocarbons
organic molecules consisting of only carbon and hydrogen
-undergo reactions that release a large amount of energy
Isomers
compounds with the same molecular formula but different structures and properties
Structural isomers
different cavalry arrangements of their atoms
Cis-trans isomers
have the same covalent bonds but differ in spatial arrangements
cis=same side
trans=opposite sides
Enantiomers
ironers that are mirror images of each other
Functional groups
-the components of organic molecules that are most commonly involved in chemical reactions
-replace the hydrogens attached to skeletons of organic molecules
-the number and arrangement of functional groups give each molecule its unique properties
Hydroxyl group
-OH
-alcohols
-polar since electrons spend more time near electronegative oxygen atom
-can form hydrogen bonds with water and dissolve organic compounds
Carbonyl
C double bond to O
-ketones= if carbonyl group is within a carbon skeleton
-aldehydes- if carbonyl group is at end of carbon skeleton
-found in sugars ketoses(contain ketones) and aldoses(contain aldehydes)
Carboxyl
C double bond to O single bond to OH
-carboxylic acids, organic acids
-acts as an acid, donate an H+ because covalent bond between o and h is so polar
-found in cells in ionized form with -1 charge- called a carboxylate ion
Amino
N single bond to H single bond to H
-amines
-acts as base, picks up H+ from surrounding solution
-found in cells in ionized form with +1 charge
Sulfhydryl
-SH
-thiols
-2 sulfhyryl groups can react forming a covalent bond, cross linking helps stabilize protein structure
Phosphate
P double bond to O, single bond to 3 other Os
-organic phosphates
-contributes negative charge to molecule (-2 when at end, -1 when internally located in chain of phosphates), potential to react with water and release energy
Methyl
C single bond to 3 Hs
-methylated compounds
-addition to dna affects expression of genes, arrangement affects shape and function of sex hormones