Chapter 20 Flashcards
What is a bronsted Lowry acid
Bronsted Lowry acid is a proton donor
What is a bronsted Lowry base
Bronsted Lowry base is a proton acceptor
What is a monobasic dibasic and tribasic acid
A monobasic acid can only released one proton a dibasic could release two and a tribasic can release 3
What are conjugate acid base pairs
Conjugate pairs and linked by the transfer of a proton the species that has lost a proton is a conjugate base and a species that is gaining a proton is a conjugate acid
Why is water a special case for conjugate acid base pairs
With acids water forms a conjugate acid where is with bases it forms a conjugate base
Describe the development of the acid-base theory
In 1754 Guillame said a base react with an acid to give a solid form
In 1884 Arhenius says acid forms h+ ions and bases form oh- ions
In 1923 bronsted Lowry says an acid donates a proton and a base accepts it
Acid + metal=
Acid + metal= salt + hydrogen
Acid + carbonate
Acid + carbonate= salt + water + carbon dioxide
Acid + base
Acid + base= salt + water
Acid + alkali
Acid + alkali=salt + water
What does pH measure
pH measures the concentration of hydrogen ions in solution
pH=
pH= -log|H+|
|H+|=
|H+|= 10^-pH
What assumption is made for strong acids
Concentration of acid is equal to concentration of h+ ions
What is the acid dissociation constant Ka
KA is the equilibrium constant that shows the extent of dissociation of a weak acid
Ka=
Ka= |H+| |A-| / |HA|
What is PKa
PKa is a negative logarithm of Ka
Ka=
In terms of pKa
Ka= 10-pKa
pKa=
pKa=-logKa
What is the difference between a strong acid and a weak acid
A strong acid completely dissociates and a weak acid partially dissociates
What approximations are made with weak acids
H A produces equal concentrations of h plus and a minus
Ha is larger than H+
The dissociation of water is negligible
In weak acids Ka=
Ka= |H+|^2/ |HA|
What is the ionic product of water kW
kW is the product of ions formed in the partial dissociation of water
kW=
kW= |H+| |OH-|
What is kw at 25 degrees
kW= 1x10-14 mol2dm-6
Does temperature affect kW
Temperature varies the value of kW
Does concentration affect kW
Concentration affect kW