Chapter 17 Keywords Flashcards
Fragmentation
The proces by which some of the molecular ion breaks down into fragments making fragment ions.
Simplest fragmentation breaks molecular ion into a fragment ion and a radical. Positive ions are detected and radicals aren’t.
ITF when m/z =15
CH3+
ITF when m/z = 29
C2H5+
ITF when m/z =43
C3H7+
ITF when m/z = 57
C4H9+
Stretch
A type of vibration, Rhythmic movement along the line between atoms meaning that the distance between the two atomic centres increases and decreases
Bend
A type of vibrato not resulting in the change in bond angle
Fingerprint region
Below 1500cm-1, used to identify the particular molecule under investigation either by using computer software or by physically comparing the spectrum to booklets published spectra.