Chapter 14 Test Flashcards

1
Q

What is the atomic radius?

A

half the distance between the nuclei of two alike atoms when bonded together in an atomic molecule.

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2
Q

How are atomic radii trending in groups?

A

Increases as you move down a group

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3
Q

Why do atomic radii increase as you go down a group?

A

There are more energy levels, which causes the atom to be larger.

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4
Q

Describe the Shielding Effect with respect to atomic radius.

A

With each additional energy level, these inner energy levels block the pull of the nucleus on the outer electrons.

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5
Q

What is the Shielding Effect?

A

When inner energy levels block the pull of the nucleus on the electrons of the outer energy levels.

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6
Q

How does atomic radius trend in a period?

A

Decreases as you move to the right in a period.

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7
Q

Why does atomic radius trend in a period?

A

There is increased nuclear charge as you move right in a particular period, without adding another energy level, so the electrons are pulled closer to the nucleus and atomic size decreases.

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8
Q

Describe the Shielding Effect’s trends.

A

Increases going down a group, remains constant in the same period.

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9
Q

What is Ionization energy?

A

The amount of energy needed to remove an electron from an atom

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10
Q

What is the symnbol for ionization energy?

A

IE

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11
Q

How does IE trend in a group?

A

As you go down a group, the energy decreases

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12
Q

Why does IE trend the way it does in groups?

A

The larger the atom, the less energy needed to remove electrons from it because the nucleus has a weaker threshold on the outer electron shells.

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13
Q

How does IE trend in a period?

A

As you go right in a period, this increases

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14
Q

Why does IE trend the way it does in periods?

A

The nuclear charge increases, which decreases the size of the atom, as more eletrons are added. Becuase the electrons are held tighter together, it will take more energy to pull off those electrons because of the strong hold it has.

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15
Q

Describe the relation between Shielding Effect and IE.

A

Because Shielding Effect increases, outer electrons aren’t held as tightly, so they are easier to remove and this requires less energy and a lower IE.

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16
Q

Are noble gases part of the periodic trends? Explain.

A

No. They are completely stable, so they do not want to gain or lose any electrons. They are only counted for atomic radius because of their number of electrons.

17
Q

Which elements have the largest and smallest atomic radius?

A

Francium-largest

Helium-smallest

18
Q

Which elements have the highest and lowest IE?

A

Francium-lowest

Fluorine-highest

19
Q

Which elements have the highest and lowest electronegativity?

A

Francium-lowest

Fluorine-highest

20
Q

Why are the alkali metals so reactive?

A

They are the largest elements and have the lowest IE, so any electron can be removed at any time, which makes them quickly react.

21
Q

What is the first IEs?

A

The energy needed to remove the first electron from an atom.

22
Q

What is the second IE?

A

The energy needed to remove the second electron from an atom.

23
Q

When does a large jump occur in IE for an atom? Why does it do this?

A

When the atom attains noble gas electron configuration. It does this because it would take much more IE to remove one more atom from the noble gas configuration because it is most stable at a noble gas.

24
Q

What is the symbol for electronegativity?

A

EN

25
Q

What is electronegativity?

A

The tendency of an atom to attract electrons to itself when bonding to another atom.

26
Q

How does EN trend in groups?

A

It goes down as you move down a group.

27
Q

How does EN trend in periods?

A

It goes up as you move right in a period.

28
Q

Why does EN decrease during its trend in groups?

A

As you increase the number of energy levels and the Shielding Effect, atoms get larger, which means outer electrons are not held as tightly, so the atom has a lower ability to attract electrons to itself.

29
Q

Why does EN increase as you move across a period?

A

As nuclear charge increases across a period, atoms become smaller, thus holding their electrons closer and tighter, therefore having a greater ability to attract electrons, let alone hold on to their own.

30
Q

Which elements have highest and lowest EN?

A

Fluorine-highest

Francium-lowest

31
Q

How does Shielding Effect relate to energy levels?

A

If energy level size is larger, even though positive charges go up more by each period, the atom gets bigger because the spread of each energy level is larger.

32
Q

What is the ionic radius?

A

The size of an ion

33
Q

How does ionic radius trend in groups? Periods?

A

Increases down a group (same reasons as atomic radius)

Decreases across a period (same reasons as atomic radius)

34
Q

Why are cations always smaller than their neutral atoms?

A

Less electron repulsion is present because they lose electrons and are more positive.

35
Q

Why are anions always bigger than their neutral atoms?

A

More electron repulsion is present because they gain more electrons in bonding and are more negative.

36
Q

Why do metals form cations and nonmetals for anions?

A

They lose electrons to be noble, and they are easy to pull off electrons. Nonmetals are tighter, harder to pull apart because they have more electrons to start with and they have to gain to be noble.

37
Q

Describe EN, IE, AR, and IR with relation to metals and nonmetals.

A

Metals: low EN and IE
Nonmetals: high EN and IE