Chapter 13 - Alkenes Flashcards

1
Q

Unsaturated hydrocarbon

A

Has a C=C double bond

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2
Q

Pi bond

A

Formed by the sideways overlap of the two p-orbitals, one from each carbon of the double bond

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3
Q

Stereoisomers

A

Have the same structural formula but a different arrangement of the atoms in space

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4
Q

E/Z isomerism

A

Occurs due to rotation around the C=C being restricted due to the Pi bond

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5
Q

Cis-trans isomerism

A

The name used to describe a special case of E/Z isomerism

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6
Q

Addition reaction (of alkenes)

A

A reaction in which a reaction is added to an unsaturated molecule to make one saturated molecule

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7
Q

Hydrogenation

A

When the alkene is mixed with hydrogen and passed over a nickel catalyst at 423K to form an alkane

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8
Q

Halogenation

A

Alkenes undergo a rapid addition reaction with the halogens, chlorine or bromine at room temperature to form a haloalkane

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9
Q

Addition reactions with hydrogen halides

A

Alkenes react with gaseous hydrogen halides at room temperature to form haloalkanes

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10
Q

Hydrogen reactions with alkenes

A

Alcohols are formed when alkenes react with steam in the presence of an phosphoric acid catalyst

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11
Q

Electrophile

A

An atom or group of atoms that is attracted to an electron rich centre and accepts an electron pair

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12
Q

Polymers

A

Extremely large molecules formed from many thousands of repeat units of smaller molecules known as monomers

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