Chapter 13 - Alkenes Flashcards
Unsaturated hydrocarbon
Has a C=C double bond
Pi bond
Formed by the sideways overlap of the two p-orbitals, one from each carbon of the double bond
Stereoisomers
Have the same structural formula but a different arrangement of the atoms in space
E/Z isomerism
Occurs due to rotation around the C=C being restricted due to the Pi bond
Cis-trans isomerism
The name used to describe a special case of E/Z isomerism
Addition reaction (of alkenes)
A reaction in which a reaction is added to an unsaturated molecule to make one saturated molecule
Hydrogenation
When the alkene is mixed with hydrogen and passed over a nickel catalyst at 423K to form an alkane
Halogenation
Alkenes undergo a rapid addition reaction with the halogens, chlorine or bromine at room temperature to form a haloalkane
Addition reactions with hydrogen halides
Alkenes react with gaseous hydrogen halides at room temperature to form haloalkanes
Hydrogen reactions with alkenes
Alcohols are formed when alkenes react with steam in the presence of an phosphoric acid catalyst
Electrophile
An atom or group of atoms that is attracted to an electron rich centre and accepts an electron pair
Polymers
Extremely large molecules formed from many thousands of repeat units of smaller molecules known as monomers