chapter 1 part 2 Flashcards

1
Q

energy state

A

a sublevel where an electron or two can reside

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2
Q

solution to a wave functions

A

positive, negative or ze3ro

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3
Q

constructive interference

A

wave functions with the same phase sign interact= reinforcing affect; amplitude increases

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4
Q

destructive interference

A

wave functions with opposite phases interact and there is a subtractive effect; the amplitude of the wave function goes into zero or the sign chances

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5
Q

orbital

A

region of space with a high probability of finding an electron

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6
Q

energy of the 1st and 2nd principal shells

A

-electrons in 1s orbital have the lowest energy
-electrons in 2p orbitals have equal but higher energy than 2s

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7
Q

degenerate orbitals

A

orbitals of equal energy

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8
Q

aufbau principle

A

orbitals are filled so that the ones of the lowest energy are filled first

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9
Q

pauli exclusion principle

A

maximum of two electrons may be placed in each orbital but only when the spins of the electrons are paired

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10
Q

hund rule

A

degenerate orbitals are given one electron with their spins unpaired until each of them contains one electron then you add second electrons to each degenerate so that the spins are paired

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11
Q

atonic orbitals

A

one or two electrons on an atom are likley to be found

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12
Q

molecular orbial

A

where electrons on a molecule are likley to be found

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13
Q

what happens when atomic orbitals combine to form molecular obritals

A

the number of molecular orbitals that results always equals the number of atomic orbitals that combine

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14
Q

bonding molecular orbital

A

two orbitals of the same phase overlap

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15
Q

antibonding molecular orbital

A

two orbitals of opposite phase interact

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16
Q

hybridization

A

atomic orbitals mixing (not molecular); forms new identical hybrid orbitals

17
Q

ressonance

A

electrons cant NEVER move from a positive; they go from negative to positive or neutral areas
-never break octet of the second row
-shows where regions of high and low electron density are (with the charges)

18
Q

second row elements

A

(CNOF) have only 4 valence electrons and therefore only 4 valence orbitals (they can NEVER make 5 bonds)

18
Q

second row elements

A

(CNOF) have only 4 valence electrons and therefore only 4 valence orbitals (they can NEVER make 5 bonds)

19
Q

negative carbon

A

region of high electron density