alkynes Flashcards
hybridization of triple bonc c
sp and linear geometry
how to draw alkynes
must draw them linear
-NO BENDING
terminal alkyne
has a proton/h connected directly to the triple bond
internal alkyne
no proton/ h
removing h from terminal alkyne/ deprotonate
USE A STRONG BASE
-result is a conjugate base/ alkynide ion
-the ion is a strong nu for an sn2 rxn but the substrate must be a methyl halide or primary halide
base used to deprotonate
must be less stable (a stronger base) than the resulting alkynide ion
-use ario to determine stability
-nah or nanh2
ario
-stability increases as you go right
-sp is more stable
alkyne synth
treat a germinal dihalide or vicinal dihalide w a strong base
-requires two moles of base for every more of dihalide ex nah2
-product is an alkynide salt that gets protonated
-it is 2 e2 reactions happening
protonate
take a proton and put it on the negative charage/ atom w out H
alkylation
doing sn2 w ion and useing the ion as a nu
-step 1= convert alkyne to ion with nanh2 (strong base)