alkynes Flashcards

1
Q

hybridization of triple bonc c

A

sp and linear geometry

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2
Q

how to draw alkynes

A

must draw them linear
-NO BENDING

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3
Q

terminal alkyne

A

has a proton/h connected directly to the triple bond

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4
Q

internal alkyne

A

no proton/ h

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5
Q

removing h from terminal alkyne/ deprotonate

A

USE A STRONG BASE
-result is a conjugate base/ alkynide ion
-the ion is a strong nu for an sn2 rxn but the substrate must be a methyl halide or primary halide

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6
Q

base used to deprotonate

A

must be less stable (a stronger base) than the resulting alkynide ion
-use ario to determine stability
-nah or nanh2

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7
Q

ario

A

-stability increases as you go right
-sp is more stable

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8
Q

alkyne synth

A

treat a germinal dihalide or vicinal dihalide w a strong base
-requires two moles of base for every more of dihalide ex nah2
-product is an alkynide salt that gets protonated
-it is 2 e2 reactions happening

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9
Q

protonate

A

take a proton and put it on the negative charage/ atom w out H

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10
Q

alkylation

A

doing sn2 w ion and useing the ion as a nu
-step 1= convert alkyne to ion with nanh2 (strong base)

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