Ch8 Periodic table and periodicity Flashcards
Periodic table arrangement of elements
- by increasing atomic number
- in periods showing repeating trends in physical and chemical properties
- in groups have similair chemical properties
periodicity
repeating pattern, in either physical or chemical properties, across different periods
First ionisation energy
energy required to remove one electron from the ground state of each atom in one mol of gaseous atoms of that element to form one mol if gaseous 1+ ions
Trend in first ionisation energy down a group
Decreases
- atomic radius increases
- shielding effect increases down group
- nuclear charge increases(outweighed by other factors)
Trend in first ionisation energy across a period
General Increase
- atomic radius decreases
- nuclear charge increases
- shielding effect generally remains same
Slight decrease in first ionisation energy
after 2nd and 5th element
elements in group 3- s electrons provide greater shielding of p electron, which is therefore lost more readily
elements in group 6- have pair of p electrons and repulsion is sufficient to make them ionise slightly more readily
atomic radius
the further the electron is away from the nucleus the easier it is to remove an electron due to less attraction to nucleus
nuclear charge
as number of protons in nucleus increases its attraction to outermost electrons increases
shielding effect
electrons in inner shells exert repelling effect on outermost electrons in outer shell- reducing pull of nucleus on outer electrons