Ch6 Types of reaction- precipitation, acid-base and redox Flashcards

1
Q

precipitation reaction

A

cation and anion in solution combine to form an insoluble substance that precipitates out as a solid

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2
Q

Anions

A

negative ions

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3
Q

Cations

A

positive ions

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4
Q

Redox reaction

A

Electrons are transferred from one substance to another

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5
Q

Rules of oxidation numbers

A
  1. all elements in natural state have oxidation number 0
  2. oxidation numbers of atoms of any molecule add up to 0
  3. oxidation number of components of any ion add up to charge on that ion
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6
Q

Oxidation order of priority

A
  1. Group 1,2 and 3 oxi no’s are always +1,+2 and +3 respectively
  2. oxidation number of fluorine is always -1
  3. oxidation number of hydrogen is normally +1
  4. oxidation number of oxygen is normally -2
  5. the oxidation number of chlorine is usually -1
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7
Q

oxidising agent

A

encourages oxidation- substance that receives electrons readily

e.g. group 7

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8
Q

reducing agent

A

encourages reduction- substance that donates electrons readily

e.g. group 2

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9
Q

Trends for redox down group 2

A

More likely to lose electron
More easily oxidised
Becomes better reducing agent

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10
Q

Trends for redox down group 7

A

Less likely to gain an electron
Less easily reduced
Becomes worse oxidising agent

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11
Q

Acids pH

A

below 7

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12
Q

Alkali pH

A

above 7

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13
Q

Strong Acid

A

proton donor that completely dissociates its ions in water

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14
Q

Weak acid

A

proton donor that only partially dissociates into its ions in water

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15
Q

Strong acid examples

A

Hydrochloric acid HCl
Sulfuric acid H2SO4
Nitric acid HNO3

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16
Q

Weak acid examples

A

Phosphoric acid H3PO4
Ethanoic acid CH3COOH

17
Q

Base

A

reacts with H+ ion released by acid
proton acceptor

18
Q

Alkali

A

soluble base- can accept protons in solution
release OH- ions in water

19
Q

Alkali examples

A

Sodium hydroxide NaOH
Potassium hydroxide KOH
Ammonia NH3

20
Q

Role of water in acidity and alkalinity

A

water must be present for substances to act as acids and alkalis

Release H+ ions/ OH- ions when dissolved in water

21
Q

Salt

A

When an acid has one or more of it’s hydrogen ions replaced by either a metal ion or ammonium ion

22
Q

Different neutralisation reactions

A
  • acid + alkali
  • acid + base
  • acid + carbonate
  • acid + metal
23
Q

Sequence of ion tests

A

Carbonate
Sulfate
Halide

24
Q

Test for carbonate ions

A

Add dilute HCl
If effervescence is given off, CO2 gas has been given off and carbonate is present

25
Q

Test for Sulfate ions

A

Add solution of barium chloride(BaCl2)
If white precipitate is formed(BaSO4) a sulfate is present

26
Q

Test for ammonium ions

A

Warm NH4+ with dilute sodium hydroxide
NH3(g) is produced turning moist red litmus blue

27
Q

Reaction of acid + base/alkali

A

Produces salt and water

28
Q

Reaction of acid + carbonate

A

Produces salt, water and carbon dioxide

29
Q

Reaction of acid + metal

A

Produces salt and hydrogen gas

30
Q

Disproportionation reaction

A

When the same element both increases and decreases its oxidation numbers so that the element is simultaneously oxidised and reduced