Ch6 Types of reaction- precipitation, acid-base and redox Flashcards
precipitation reaction
cation and anion in solution combine to form an insoluble substance that precipitates out as a solid
Anions
negative ions
Cations
positive ions
Redox reaction
Electrons are transferred from one substance to another
Rules of oxidation numbers
- all elements in natural state have oxidation number 0
- oxidation numbers of atoms of any molecule add up to 0
- oxidation number of components of any ion add up to charge on that ion
Oxidation order of priority
- Group 1,2 and 3 oxi no’s are always +1,+2 and +3 respectively
- oxidation number of fluorine is always -1
- oxidation number of hydrogen is normally +1
- oxidation number of oxygen is normally -2
- the oxidation number of chlorine is usually -1
oxidising agent
encourages oxidation- substance that receives electrons readily
e.g. group 7
reducing agent
encourages reduction- substance that donates electrons readily
e.g. group 2
Trends for redox down group 2
More likely to lose electron
More easily oxidised
Becomes better reducing agent
Trends for redox down group 7
Less likely to gain an electron
Less easily reduced
Becomes worse oxidising agent
Acids pH
below 7
Alkali pH
above 7
Strong Acid
proton donor that completely dissociates its ions in water
Weak acid
proton donor that only partially dissociates into its ions in water
Strong acid examples
Hydrochloric acid HCl
Sulfuric acid H2SO4
Nitric acid HNO3
Weak acid examples
Phosphoric acid H3PO4
Ethanoic acid CH3COOH
Base
reacts with H+ ion released by acid
proton acceptor
Alkali
soluble base- can accept protons in solution
release OH- ions in water
Alkali examples
Sodium hydroxide NaOH
Potassium hydroxide KOH
Ammonia NH3
Role of water in acidity and alkalinity
water must be present for substances to act as acids and alkalis
Release H+ ions/ OH- ions when dissolved in water
Salt
When an acid has one or more of it’s hydrogen ions replaced by either a metal ion or ammonium ion
Different neutralisation reactions
- acid + alkali
- acid + base
- acid + carbonate
- acid + metal
Sequence of ion tests
Carbonate
Sulfate
Halide
Test for carbonate ions
Add dilute HCl
If effervescence is given off, CO2 gas has been given off and carbonate is present
Test for Sulfate ions
Add solution of barium chloride(BaCl2)
If white precipitate is formed(BaSO4) a sulfate is present
Test for ammonium ions
Warm NH4+ with dilute sodium hydroxide
NH3(g) is produced turning moist red litmus blue
Reaction of acid + base/alkali
Produces salt and water
Reaction of acid + carbonate
Produces salt, water and carbon dioxide
Reaction of acid + metal
Produces salt and hydrogen gas
Disproportionation reaction
When the same element both increases and decreases its oxidation numbers so that the element is simultaneously oxidised and reduced