Carbohydrates Lec Flashcards
Characterized as either monosaccharides, disaccharides, or polysaccharides
carbohydrates
biomolecules that are composed of carbon, hydrogen, and oxygen atoms in the ratio of 1:2:1 (CH2O)
carbohydrates
building blocks (monomers) of all carbohydrates
monosaccharides
examples of monosaccharides
glucose
fructose
galactose
most abundant monosaccharide, water soluble, and easily transported through an organism (
glucose
found in fruits and plants
fructose
sugar found in milk
galactose
formed when monosaccharides are joined together through dehydration reactions forming glycosidic linkages
disaccharides
made up of two glucose molecule, malt sugar
maltose
glucose and fructose, table sugar),
sucrose
made up of glucose and galactose, milk sugar
lactose
formed when glucose monomers link together to form long chains
polysaccharides
Include starch, cellulose, chitin, and peptidoglycan
polysaccharide
most abundant polysaccharide (straight chain polymer of glucose, but configuration is different
cellulose
structure polysaccharide found in insects and crustaceans
chitin
found in cell walls of bacteria
peptidoglycan
major class of biomolecules that is literally formed by hydration of carbon atoms, Cn-(H2O)n.
carbohydrates
polyhydroxy aldoses or ketoses which can be represented by the planar Fischer projection
monosaccharide
structure where carbohydrates exist biologically
haworth structure
cyclic structure due to the intramolecular reaction between the carbonyl carbon and hydroxyl group of the reference carbon
hemiacetal or hemiketal
five-membered cyclic ether
furan
six-membered cyclic ether
pyran
three-carbon monosaccharide
triose
carbohydrates with two sugar units that are linked by an O-glycosidic bond that is formed by condensation of two hydroxyl (-OH) groups into an ether bond
disaccharides
carbohydrates with two sugar units that are linked by an O-glycosidic bond that is formed by condensation of two hydroxyl (-OH) groups into an ether bond
disaccharides
those with free hydroxyl group (-OH) on the anomeric center
reducing disaccharide
have no free hydroxyl group in their anomeric cente
nonreducing disaccharide
draw lactose and its systematic name
galactose and glucose (1-4)
+1
draw sucrose
a-glucose
b-fructose (1->2)
+1
made up of numerous sugar units usually in the hundreds and even thousands
polysaccharides
include starch and glycogen, which serve as energy reserves of living organisms
function of polysaccharides?
storage
penultimate storage form of glucose in plants and is made up of two distinct macromolecules called α-amylose and amylopectin
starch
strach is made up of
a-amlyose
amylopectin
has linear chain of glucose subunits that are connected by α(1->4) O-glycosidic bond
a-amylose
same linear glucose chain base as in α-amylose but has a α(1->6) glucose branch for every 24-30 glucose residues
amylopectin
storage form of glucose in animals and humans which has a similar structure to amylopectin except that the
α(1->6) branching occurs more frequently at around 8-12 glucose residues
glycogen
identify the structures in amylose, amylopectin, and glyocen
+1
two beta glucose unit disaccharide
cellobiose
beta-galactose and alpha-glucose
lactose
alpha-glucose and beta-fructose
sucrose
3 to 10 saccharide units
oligosaccharide
considerably reactive in carbohydrates
what groups
carbonyl
hydroxyl
type of reaction where aldehydes and alcohols are turned to carboxylic acids
oxidation
what is benedict’s solution
CuSO4 in NaOH (copper sulfate in sodium hydroxide)
what is tollen’s reagent
AgNO3 in NH3
(silver nitrate in ammonia)
product when weak oxidizing agent like (Br2 in H2O, CuSO4 in NaOH, and AgNO3 in NH3) oxidize the aldehyde group
aldonic acid
aldonic acid is produced when the aldehyde is oxidized using what reagents
Br2 in H2O (bromide in water)
CUSO4 in NaOH (copper sulfate in sodium hydroxide)
AgNO3 in NH3 (silver nitrate in ammonia)
product when the enzymatic oxidation of the terminal alcohol of monosaccharide
alduronic acid
enzyme that can turn into alduronic acid
oxidase
bayer’s reagent is made up of
Potassium Permanganate (KMnO4)
product when strong oxidizing agents like HNO3 or KMnO4 oxidize both aldehyde and terminal alcohol groups
Aldaric acid