Carbohydrates Flashcards

1
Q

What is the primary function of carbohydrates

A

provide the body with energy

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2
Q

what are carbohydrates broken down into

A

glucose

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3
Q

what happens if the body has enough glucose to fill its current needs

A

excess glucose is stored for later use in the form of glycogen and is mostly found in liver and skeletal muscle

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4
Q

what does dietary fiber contain

A

indigestible carbohydrates

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5
Q

what are carbohydrates made up of

A

monosaccharides

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6
Q

what does a monosaccharide consist of

A

carbon, hydrogen, and oxygen

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7
Q

what is an aldose

A

carbonyl group is bonded to at least 1 hydrogen

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8
Q

what is a ketose

A

carbonyl group is bonded to 2 carbons

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9
Q

what is ā€œDā€ in carbon numbering

A

highest number chiral carbon farthest from aldehyde or keto group with hydroxyl group to the right

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10
Q

what do carbohydrates form in aqueous solution

A

ring structures

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11
Q

Condensation reaction

A

glycosidic bond (covalent) forms between a hydroxyl group of one molecule and the anomeric carbon of another

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12
Q

anomeric carbon

A

carbon that was the carbonyl carbon in acyclic form.
found next to the oxygen atom in the ring but on the opposite side of the carbon that carries the CH2OH (hydroxymethyl) group in acyclic form

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13
Q

sucrose

A

disaccharide
glucose + fructose

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14
Q

lactose

A

glucose + galactose

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15
Q

maltose

A

glucose + glucose

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16
Q

how many monosaccharides do oligosaccharides have

A

3 - 12

17
Q

examples of oligosaccharides

A

immunoglobulin, mucin

18
Q

what are oligosaccharides covalently bonded to

A

proteins.
primarily located on the surface of cells or in the ECM

19
Q

how many monosaccharides do polysaccharides consist of

A

> 12

20
Q

glycan

A

synonym for oligosaccharides and polysaccharides

21
Q

proteoglycans

A

constitute a major component of the extracellular matrix

22
Q

examples of polysaccharides

A

glycogen, starch, cellulose, glycosaminoglycan

23
Q

gylcogen

A

composed of alpha glucose monomers with extensive branching.
storage form of glucose in animals.
located mainly in liver and muscle

24
Q

starch

A

composed of alpha glucose monomers with or without branching.
- branching (amylopectin)
- unbranched (amylose)
storage form of glucose in plants

25
Q

cellulose

A

composed of beta glucose monomers with no branching.
humans are unable to digest cellulose due to lack of enzymes to break down beta glucose linkages
- contributes to formation of dietary fiber

26
Q

glycosaminoglycan (GAG, mucopolysaccharide)

A

composed of repeating disaccharide units (amino sugar and uronic acid or galactose) without branching

27
Q

5 groups of GAGs

A
  1. Chrondroitin sulfate: most abundant
  2. Keratan sulfate: abundant; originally in cornea
  3. Dermatan sulfate: mainly in skin
  4. Heparan sulfate: all animal tissues
  5. Hyaluronate: ECM; 1st isolated in vitreous humor; only GAG not sulfated
28
Q

are glycosaminoglycans (GAGs) negatively or positively charged

A

highly negatively charged.
attracts water.
functions as a lubricant or shock absorbed due to high viscosity and low compressibility

29
Q

where are GAGs located

A

primarily on the surface of cells or in the ECM.
fill the space of the ECM in the form of a hydrated gel

30
Q

what are most GAGs linked to

A

core protein, forms proteoglycan.
GAGs extend perpendicular from the core protein in a bottlebrush-like structure

31
Q

what GAG is not linked to a core protein

A

hyaluronate

32
Q

examples of proteoglycans

A

Aggrecan
Lumican
Keratocan
Mimecan
Decorin

33
Q
A