Carbohydrates Flashcards

1
Q

can be used to refer to carbohydrates as a whole.

also a polymer.

A

Sugar

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2
Q

What is the building blocks of carbohydrates/sugar

A

monosaccharide

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3
Q

monosaccharide contains

A

Aldehyde and ketones

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4
Q

A polyhydroxyaldehyde or

polyhydroxyketone

A

Carbohydrate / sugar

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5
Q

Aldehyde compound with many hydroxyl groups attached to the aldehyde parent

A

polyhydroxyaldehyde

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6
Q

Ketone compound with many hydroxyl groups attached to the ketone parent

A

Polyhydroxy Ketone

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7
Q

T OR FALSE

Carbohydrate is a substance that can form polyhydroxyaldehyde or
polyhydroxyketone

A

TRUE

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8
Q

A carbohydrate that cannot be hydrolyzed to a simpler carbohydrate.

A

Monosaccharide:

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9
Q

Monosaccharides have the general formula of

A

CnH2nOn

where n varies from 3 to 8.

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10
Q

A monosaccharide containing an aldehyde group.

A

Aldose:

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11
Q

Aldehyde functional group:

A

−CHO

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12
Q

A monosaccharide containing a ketone group.

A

Ketose:

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13
Q

Ketone functional group:

A

R2C=O

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14
Q

The suffix that indicates that a molecule is a carbohydrate.

A

-ose

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15
Q

The prefixes indicate the

A

carbon atoms in the chain

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16
Q

There are only two trioses:

A

aldotriose (glyceraldehyde)

Ketotriose (dyhydroxyacetone)

17
Q

T OR F

the two trioses are functional isomers. They contain the
same molecular formula.

18
Q

The structure has a lot of oxygen, that’s why these

structures love

19
Q

Because of the number of oxygen here associated

with the carbon, these types of molecules are already

A

partially oxidized

When we say that the molecule is oxidized, then the carbon has more bonds with oxygen.

20
Q

The most oxidized carbon

A

CO2

For example, carbon dioxide (CO2), with the structure
O=C=O. This carbon is the most oxidized carbon
because it has four bonds with oxygen.

21
Q

the metabolic cycle where we would see
carbon dioxide being produced. By tracing this
pathway, we can measure the amount of energy we
can get from them.

A

KREBS CYCLE

22
Q

What is the simplest aldose

A

glyceraldehyde

contains one
stereocenter and exists as a pair of enantiomers.

23
Q

All of the monosaccharides have chiral centers except for

A

Dihydroxyacteone

24
Q

A two-dimensional representation for showing the configuration of tetrahedral stereocenters.

A

FISCHER PROJECTION

25
pertains to the last chiral carbon farthest from the functional group. This would be the reference point whether you would call the molecule D or L.
Penultimate carbon
26
chiral requires a carbon to have
have different | four functional groups attached to it.
27
The three most common D-hexoses.
D-glucose D-galactose D-glucosamine
28
sugars have amino substituents.
AMINO SUGARS
29
contain an -NH2 group in place of an -OH | group.
AMINO SUGARS
30
the only three amino sugars common in nature:
D-glucosamine, D-mannosamine, and | D-galactosamine.
31
The cyclic structure is brought about by a reaction of either the
aldehyde group or keto group with alcohol
32
T OR F predominant forms of monosaccharides follow the Fischer projection
FALSE they are in CYCLIC
33
Aldehydes and ketones react with alcohols to form
Hemiacetals Cyclic hemiacetals form readily when hydroxyl and carbonyl groups are part of the same molecule and their interaction can form a five- or six-membered ring.