Carbohydrates Flashcards

1
Q

can be used to refer to carbohydrates as a whole.

also a polymer.

A

Sugar

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2
Q

What is the building blocks of carbohydrates/sugar

A

monosaccharide

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3
Q

monosaccharide contains

A

Aldehyde and ketones

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4
Q

A polyhydroxyaldehyde or

polyhydroxyketone

A

Carbohydrate / sugar

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5
Q

Aldehyde compound with many hydroxyl groups attached to the aldehyde parent

A

polyhydroxyaldehyde

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6
Q

Ketone compound with many hydroxyl groups attached to the ketone parent

A

Polyhydroxy Ketone

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7
Q

T OR FALSE

Carbohydrate is a substance that can form polyhydroxyaldehyde or
polyhydroxyketone

A

TRUE

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8
Q

A carbohydrate that cannot be hydrolyzed to a simpler carbohydrate.

A

Monosaccharide:

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9
Q

Monosaccharides have the general formula of

A

CnH2nOn

where n varies from 3 to 8.

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10
Q

A monosaccharide containing an aldehyde group.

A

Aldose:

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11
Q

Aldehyde functional group:

A

−CHO

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12
Q

A monosaccharide containing a ketone group.

A

Ketose:

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13
Q

Ketone functional group:

A

R2C=O

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14
Q

The suffix that indicates that a molecule is a carbohydrate.

A

-ose

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15
Q

The prefixes indicate the

A

carbon atoms in the chain

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16
Q

There are only two trioses:

A

aldotriose (glyceraldehyde)

Ketotriose (dyhydroxyacetone)

17
Q

T OR F

the two trioses are functional isomers. They contain the
same molecular formula.

A

true

18
Q

The structure has a lot of oxygen, that’s why these

structures love

A

water

19
Q

Because of the number of oxygen here associated

with the carbon, these types of molecules are already

A

partially oxidized

When we say that the molecule is oxidized, then the carbon has more bonds with oxygen.

20
Q

The most oxidized carbon

A

CO2

For example, carbon dioxide (CO2), with the structure
O=C=O. This carbon is the most oxidized carbon
because it has four bonds with oxygen.

21
Q

the metabolic cycle where we would see
carbon dioxide being produced. By tracing this
pathway, we can measure the amount of energy we
can get from them.

A

KREBS CYCLE

22
Q

What is the simplest aldose

A

glyceraldehyde

contains one
stereocenter and exists as a pair of enantiomers.

23
Q

All of the monosaccharides have chiral centers except for

A

Dihydroxyacteone

24
Q

A two-dimensional representation for showing the configuration of tetrahedral stereocenters.

A

FISCHER PROJECTION

25
Q

pertains to the last chiral carbon farthest from the functional group.

This would be the reference point whether you would
call the molecule D or L.

A

Penultimate carbon

26
Q

chiral requires a carbon to have

A

have different

four functional groups attached to it.

27
Q

The three most common D-hexoses.

A

D-glucose
D-galactose
D-glucosamine

28
Q

sugars have amino substituents.

A

AMINO SUGARS

29
Q

contain an -NH2 group in place of an -OH

group.

A

AMINO SUGARS

30
Q

the only three amino sugars common in nature:

A

D-glucosamine, D-mannosamine, and

D-galactosamine.

31
Q

The cyclic structure is brought about by a reaction of either the

A

aldehyde group or keto group with alcohol

32
Q

T OR F

predominant forms of monosaccharides follow the Fischer projection

A

FALSE

they are in CYCLIC

33
Q

Aldehydes and ketones react with alcohols to form

A

Hemiacetals

Cyclic hemiacetals form readily when hydroxyl and
carbonyl groups are part of the same molecule and
their interaction can form a five- or six-membered
ring.