Carbohydrates Flashcards

1
Q

what are the common number of carbon in monosaccharides?

A

pentose

hexose

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2
Q

H-C=O is?

A

Aldehyde

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3
Q

C-C=O is?

A

Ketone (C2)

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4
Q

reactive site of molecule

where reaction takes place

A

functional group

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5
Q

T or F

FUNCTIONAL GROUP dictates the properties and characteristics of molecule

A

True

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6
Q

we commonly arrange the monosaccharides in this structure

A

Fischer Projection

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7
Q

OH is on the left side of penultimate carbon

A

L Isomer

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8
Q

Next to the Last Carbon that dictates if it’s L or D isomer

A

Penultimate Carbon (C5)

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9
Q

T or F

D isomer is more Common in Proteins
L isomer is more Common in Carbohydrates

A

False

D is more common to Carbohydrates
L is more common to Proteins

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10
Q

which is greater in number? hexose or pentose in nature?

A

hexose

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11
Q

mirror images to each other

A

Enantiomers

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12
Q

only 1 chiral center with different configuration

A

Epimers

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13
Q

not mirror images

A

diasteromers

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14
Q

T or F

D & L enantiomers are not identical when it comes to density, melting point, refractive index and boiling point.

A

False

mirror images sila kaya SAME lahat ng Physical Properties

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15
Q

T or F

it is easy to separate D and L isomer

A

False

maraming steps

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16
Q

cyclic structure

A

Haworth Projection

hemiacetal (c1-c5)
hemiketal (c2-c5)

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17
Q

T or F

in haworth projection, hydroxyl group ATTACKS the C1 to from cyclic structure

A

True

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18
Q

T or F

we place the
left side to the up
right side to the down

A

True

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19
Q

T or F

nagkakaroon ng cyclic projection pag nasa solution

A

True

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20
Q

if the monosaccharide is in the hawporth projection we add ______ as its last name

A

Pyranose

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21
Q

OH is in downward

A

Alpha Configuration

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22
Q

OH is on upward

A

Beta Configuration

23
Q

T or F

Hydrogen H+ are protonated that’s why its also prone to attack of negative molecule

24
Q

What are the Reducing Sugars?

A

All Monosaccharide

Maltose and Lactose

25
what are the Non-Reducing Sugars?
Sucrose afaik
26
it can be oxidize by weak oxidizing agent
Reducing Sugar | -can form a free carbonyl group C=0
27
T or F it is in the anomeric carbon (C1 - C5 (aldose) C2- C5 (ketose)) where we can know if it can form a free carbonyl group
True
28
What should be hydrolyzed to form free carbonyl group?
C1 or C5
29
its like Haworth projection
Chair conformation
30
T or F haworth has alpha and beta chair has axial and equatorial
True
31
In Chair configuration, OH lies downward
Axial
32
In Chair Configuration, OH lies upward
Equatorial
33
T or F Left side lies on Equatorial position
False pag Left - axial Right - equatorial
34
T or F we use anomeric carbon in fischer, haworth, chair
False sa Haworth & Chair Lang
35
bond that is sharing of electrons
Covalent Link | mono & disaccharides
36
glucose + galactose =
Lactose
37
bonds in disaccharides
Glycosidic Bond
38
T or F we can't and must not break the OXIDE BOND of disaccharides
False we can't and must not break the GLYCOSIDIC of dissacharides kasi babalik sila into monosaccharides
39
T or F it can be a reducing sugar if the Anomeric Carbon of the sugar is not covalently link to the glycosidic bond
True Glucose & Galactose (c1&c5) Fructose (c2&c5)
40
Glucose + Fructose=
Sucrose
41
T or F / beta- upward V aplha - downward
True
42
polymers of glucose in plants called starch
Amylose & Amylopectin
43
T or F Amylose is blue if cooked & release the iodine
True
44
T or F Amylopectin is violet if uncooked traps Iodine in helix structure
True
45
Glycosidic bond of Fructose
C2 & C5
46
Glycosidic Bond of Glucose & Galactose
C1 & C4
47
a (1, 4) and a (1,6) linkages
Amylopectin
48
a (1, 4) linkages
Amylose
49
if we are about to produce a free carbonyl in sucrose what carbon should we hydrolyze in fructose?
C5 of Fructose
50
Anomeric carbon of Aldose
C1
51
Anomeric Carbon of Fructose
C2
52
T or F if the anomeric carbon is involved in the glycosidic bond we can produce a free carbonyl group
False pag anomeric carbon na ang involved hindi na pwedeng maging reducing sugar
53
Carbon ____ should be breakdown to form a free carbonyl group
C5