C3 Structure and Bonding Flashcards
What is an ion?
A charged particle when an atom loses or gains electrons
What happens when metals form ions?
They lose electrons to form positive ions
What happens when nonmetals form ions?
They gain electrons to form negative ions
What happens in ionic bonding?
When a metal and nonmetal react together the metal atom transfers electrons to the nonmetal forming a positive metal ion and negative nonmetal ion. These particles are strongly attracted by electrostatic forces
What do groups one and two lose in ionic bonding?
Electrons to form positive ions
What do groups six and seven gain in ionic bonding?
Electrons to form negative ions
What is the structure of ionic compounds?
A giant ionic lattice
Ions form closely packed regular lattice with very strong electrostatic forces of attraction between the oppositely charged ions in all directions.
What are the properties of ionic compounds?
High melting points and boiling points due to the strong bonds
When solid they cannot conduct electricity
When they melt they can carry electric charge
Some dissolve easily so can carry electric charge
Why can solid ionic structures not carry electric current?
The ions are held in place so cannot conduct electricity
What is covalent bonding?
When nonmetals bond together and share pairs of electrons
What are some limits of drawing covalent bonds?
In dot and cross diagram you cannot see the relative size of the atom or how it is arranged in space
In displayed formulas you cannot see the 3-D structure or where electrons come from
3D models can get confusing with large molecules
What are some properties of simple molecular substances that are covalently bonded?
They have strong covalent bonds but weak intermolecular forces
Melting and boiling points are very low as the intermolecular forces are weak
Larger molecules have stronger intermolecular forces so the melting and boiling points of these molecules increases
They do not conduct electricity as they are not charged
What is a polymer?
A long chain molecule that is formed by joining lots of small molecules (monomers) together
What state are polymers at room temperature and why?
Solid as polymers have larger intermolecular forces so more energy is needed to break them apart
Why are the boiling points of polymers lower than ionic or giant molecular compounds?
The intermolecular forces are weaker than ionic or covalent bonds
What is the structure of a giant covalent structure?
All atoms are bonded to each other by strong covalent bonds
What are the properties of giant covalent structures?
They have very high melting and boiling points
They don’t conduct electricity
What is an allotrope?
Different structural forms of the same element in the same physical state
What is the structure of diamond?
Each carbon atom is bonded to 4 other carbon atoms with covalent bonds
Why does diamond have a very high melting point?
Strong covalent bonds take a lot of energy to break
Why does diamonds not conduct electricity?
There are no free ions
What is the structure of graphite?
Each carbon atom is covalently bonded to 3 other carbon atoms.
There is one delocalised electron.
There are no covalent bonds between layers so they are free to move over each other
What are the properties of graphite?
Graphite is soft
It has a high melting point
It conducts electricity and Thermal energy
What is graphene?
A sheet of carbon atoms join together in hexagons
It is just one atom thick
What are the properties of graphene?
It is very strong and light
It conducts electricity through the whole structure