C10 Organic reactions Flashcards

1
Q

what is the functional group of alkenes?

A

the double covalent bond between two carbon atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is the general formula for alkenes?

A

CnH2n

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

why is there no methene?

A

there has to be two carbon atoms for the carbon-carbon double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what does ‘functional group’ mean?

A

the part of the molecule which determines how it reacts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

what is a homologous series?

A

a group of molecules which all have the same functional group and react in a similar way

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is produced during the combustion of alkenes?

A

carbon dioxide, water and unburnt carbon particles due to incomplete combustion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what does it look like when alkenes burn in air?

A

they burn with a smoky flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what is hydrogenation?

A

when an alkene reacts with hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

what are the conditions for the hydrogenation of alkenes?

A

150 degrees C, nickel catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

what happens during the hydrogenation of alkenes?

A

the hydrogen atoms add across the double bond to form an alkane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what is the reaction of water and an alkene called?

A

hydration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what happens during hydration of alkenes?

A

an alcohol is produced

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what are the conditions for the hydration of alkenes?

A

water must be steam
temperature must be around 300 degrees C
pressure must be 70 atmospheres
phosphoric acid is used as a catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what is a key fact about the hydration of alkenes?

A

the reaction is reversible

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

how is the yield of an alcohol increased during the hydration of alkenes?

A

unreacted alkene and steam are passed back through the catalyst

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what happens when alkenes react with halogens?

A

the two halogen atoms add across the double bond and the double c-c bond forms a single c-c bond

17
Q

how is an alcohol formed?

A

remove an -H from an alkane
add an -OH to the alkane

18
Q

what is the functional group of alcohols?

A

-OH

19
Q

what are the first 4 alcohols?

A

methanol
ethanol
propanol
butanol

20
Q

what is the functional group of carboxylic acids?

A

-COOH

21
Q

how do you form an ester?

A

replace the H in the -COOH of a carboxylic acid and add a hydrocarbon (alkyl) group

22
Q

what is the functional group of esters?

A

-COO-

23
Q

what is fermentation?

A

the reaction in which the enzymes in yeast turn glucose into ethanol and carbon dioxide

24
Q

what does the use of ethanol as a fuel show?

A

alcohols are flammable

25
Q

how do alcohols burn?

A

with a ‘clean’ blue flame

26
Q

what is produced in the combustion of alcohols?

A

carbon dioxide
water

27
Q

how do alcohols react with sodium?

A

similar to water but less vigorous
effervescence (bubbling)
hydrogen gas is produced

28
Q

how can alcohols be oxidised (not with combustion)?

A

using chemical oxidising agents

29
Q

how can ethanol be oxidised to ethanoic acid?

A

chemical oxidising agents
microbes in the air

30
Q

what are the reactions of carboxylic acids like?

A

typical of acids
(MASH, BASHCO2, CASHCO2 ect.)

31
Q

why are carboxylic acids weak acids?

A

their molecules do not completely ionise when dissolved in water, most of the molecules stay as they are

32
Q

what is the general formula for making esters?

A

carboxylic acid + alcohol –acid catalyst–> ester + water

33
Q

what are the properties of esters?

A

distinctive smells (many are sweet and fruity)
volatile

34
Q

what are esters used for?

A

perfumes and food flavourings