C3 - Organic Chemistry Flashcards

1
Q

What does the homologous series of alcohols contain?

A

The -OH functional group.

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2
Q

What does the homologous series of carboxylic acids contain?

A

The -COOH functional group.

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3
Q

What does the homologous series of esters contain?

A

The -COO- functional group.

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4
Q

What do all organic compounds contain?

A

Carbon

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5
Q

What is a homologous series?

A

A family of compounds which all contain the same functional group.

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6
Q

What are the first three members of the homologous series of alcohols?

A
  • Methanol
  • Ethanol
  • Propanol
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7
Q

What is the formula of ethanol?

A

C2H6O

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8
Q

What is the structural formula of ethanol?

A

CH3CH2OH

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9
Q

What is ethanoic acid used in?

A

Vinegar

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10
Q

What is the structural formula of ethanoic acid?

A

CH3COOH

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11
Q

What are the first three members of the homologous series of carboxylic acids?

A
  • Methanoic acid
  • Ethanoic acid
  • Propanoic acid
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12
Q

What is the formula for ethyl ethanoate?

A

CH3COOCH2

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13
Q

Give five uses for alcohols.

A
  • Cosmetics (perfume)
  • Chemical feedstock
  • Fuel
  • Solvent
  • Alcoholic consumption
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14
Q

Give the word equation for the combustion of ethanol.

A

ethanol + oxygen —-> carbon dioxide + water

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15
Q

Give the symbol equation for the combustion of ethanol.

A

C2H5OH + 3O2 —-> 2CO2 +3H2O

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16
Q

Which gas is produced when alcohols are reacted with sodium?

A

Hydrogen

17
Q

Give the word equation for the reaction between ethanol and sodium.

A

sodium + ethanol —-> sodium ethoxide + hydrogen

18
Q

How does the reaction between sodium and alcohol compare with the reaction between sodium and water?

A

The reaction between sodium and alcohol is less vigorous.

19
Q

What is potassium dichromate (VI)?

A

A chemical oxidising agent.

20
Q

How is ethanol made into ethanoic acid?

A
  • The ethanol is boiled with acidified potassium dichromate.

- Ethanol is left exposed to the air and microbes produce ethanoic acid.

21
Q

What type of reaction occurs when ethanol is made into ethanoic acid?

A

Oxidation

22
Q

Give two ways in which carboxylic acids can be identified.

A
  • They have a pH of less than 7

- Carbonates will fizz and produce CO2.

23
Q

Why are carboxylic acids weak?

A

The molecules don’t ionise much.

24
Q

What makes a strong acid?

A

When the molecules ionise completely in solution.

25
Q

Give the word equation between ethanoic acid and sodium carbonate.

A

ethanoic acid + sodium carbonate —-> sodium ethanoate + water + carbon dioxide

26
Q

What is used as a catalyst when producing esters from carboxylic acids and alcohols?

A

Sulfuric acid

27
Q

Give the word equation for producing esters from carboxylic acids and alcohols.

A

carboxylic acid + alcohol —-> ester + water

28
Q

Give the word equation for producing methyl ethanoate.

A

ethanoic acid + methanol —-> methyl ethanoate + water

29
Q

Give two main properties of esters.

A
  • They have distinctive smells.

- They are volatile (evaporate easily)

30
Q

What can drinking methylated spirits cause?

A
  • Liver failure

- Blindness

31
Q

How are people prevented from drinking methylated spirits?

A
  • They contain emetics

- They contain foul-tasting chemicals

32
Q

How are plant oils made into biodiesel?

A
  • The oils are broken down into long-chain carboxylic acids.

- They are then reacted with methanol or ethanol to make useful esters.