c12-Org Flashcards
what are alkanes
alkanes are saturated hydrocarbons, containing only carbon and hydrogen atoms joined together by single covalent bonds
how many bonds does an alkane have to other other atoms (what type of bonds)
each carbon atom is joined to 4 other atoms by single covalent bonds called sigma bonds
what are sigma bonds
sigma bonds are the result of of the overlap of two S orbitals, one from each bonding atom, each C atom in an alkane has 4 sigma bonds
what is the shape and bond angle of alkanes
-tetrahedral arrangement
-109.5 degree bond angle
how is crude oil seperated into alkanes
fractional distillation
how does the boiling point change as the size of the alkanes increases and why
-as size increases so does the boiling point
-this is because of intermolecular forces
how do london forces affect the boiling point as th elength increases
molecules that have a large surface area will form more london forces with other molecules, therefore more energy is required to overcome these forces
why do branched isomers have lower boiling points than straight chained isomers
-branched isomers have fewer surface points of contact between molecules of the branched alkanes, giving fewer london forces
-branches get in the way and prevent the branchged molecules from getting as close together as a triaght chain molecule
why do alkanes no react with most common reagents
-sigma bonds are strong
-c-c bonds are non polar
- the electronegativity of carbon and hydrogen is so similar that the c-h bond can be considered to be non polar