Bonding Flashcards
Coulomb’s Law
(+q)(-q)/r^2
- Bigger charges mean bigger bonds, smaller charges mean smaller bonds
- Charges closer together mean stronger bonds
Ionic Bonds
- One atom takes away valence electrons from the other electron
- Usually between metals and non-metals
- Electrons held in a lattice structure-poor conductor of electrons as a solid, but good conductor as a liquid
Covalent Bonds
-Electrons are shared
- First covalent bond is a sigma bonds (σ), and all the following are pi bonds (π)
-Double and Triple Bonds are stronger than single bonds
- Sometimes electrons shared equally, but when one electronegativity is stronger than the other, electrons pulled to one side creating positive/negative side =dipole moment
Greater Charge, Larger Distance >Larger Dipole Moment> More polar
Lewis Diagram Exceptions
BeH2-> Beryllium can be stable with 4 valence elections
BF3-> can be stable with only six valence electrons
PCl5, SF4, SF6, Elements with a d-subshell can accept more than 8 valence electrons
NO and NO2 have an odd number of electrons
Network Solids
Lattice of Covalent Bonds
Hard, have a high melting point
Electrons held in a lattice, poor heat conductors
EX. compounds of carbon(diamond), SiO2
Metallic Bonds
- Sea of freely moving electrons
- Malleable and Ductile
- High boiling and melting points
- Good conductors of heat and electricity
Dipole-Dipole
- Weak bonds, low melting and boiling points
- Happens only in polar molecules
London Dispersion
- Non-polar Molecules
- Weak, low boiling and melting points
- More electrons =stronger london dispersion
Hydrogen Bonding
- When a hydrogen is bonded to N, O or F
- Stronger than di-pole di-pole
- reason why water is less dense as a solid than a liquid