Boltzmann Distribution Flashcards
Boltzmann distribution
Spread of molecular energies in gases
Area under curve=total no of molecules
Line does not meet x, no max energy for molecules
No molecules have 0 energy
Temperature and the Boltzmann distribution
Increased average energy
Small proportion will have low energy, more have high
Stretched over greater range of energy values
Peak lower on y, further along x
Same no of molecules, same area
Explanation of temperature change on distribution curve
More molecules have energy greater than/equal to AE
Larger proportion of collisions, increased r of r
Frequent collisions due to faster moving molecules due to increased KE of molecules
Explanation for catalysts and Boltzmann distribution
Cat, lower AE route
Larger proportion have energy equal to/greater than CE
Increased collisions, more product formed, increase r of r