Basic Concepts Of Organic Chemistry Flashcards
Hydrocarbons
Made up of carbon and hydrogen only
Saturated
Single bonds only
Unsaturated
Multiple bonds
Homologous series
Family of compounds with similar chemical properties, differ by addition of CH2 group
Functional group
Part of organic molecule that is responsible for molecules chemical properties
Carbon can bond to many elements
Classification of organic molecules
Aliphatic
Alicyclics
Aromatic
Aliphatic
Carbon atoms joined in unbranched or branched chains or non aromatic rings
Alicyclic
Carbon atoms joined together in cyclic structures with or without branches
Aromatic
Some/all carbons in a benzene ring
Aliphatic hydrocarbons
Alkanes
Alkenes
Alkynes
Naming molecules
Identify functional group
Identify longest carbon chain
Identify length of side groups
Names of molecules in alphabetical order
Alkene prefixes and suffixes
-ene
Alcohol prefixes and suffixes
Hydroxyl-
-ol
Haloalkane prefix and suffixes
Chloro-
Bromo-
Iodo-
Aldehyde prefix and suffixes
-al
Ketone prefix and suffixes
-one
Carboxylic acid prefix and suffixes
-oic acid
Chemical formulae
Molecular Empirical Structural Displayed Skeletal
Molecular formulae
No type of atoms present
Does not show bonding
Isomers
Empirical formulae
Simplest whole no ratio of atoms
Homologous molecules have same empirical formulae
General formulae
Simplest algebraic formula for any homologous series
General formula of alkanes
Cn H2n+2
General formula of alkenes
Cn H2n
General formula of alcohols
Cn H2n+1 OH
General formula of carboxylic acids
Cn H2n O2
General formula of ketones
Cn H2n O
Displayed formula
Relative positioning of all atoms in a molecule and bonds
Structural formula
Smallest detail necessary to show arrangement
Shows bonds
Skeletal formula
Remove all C and H
Molecules with functional groups must be included
Structural position isomers
Same molecular formula, different structural formula
Draw out the different ways that the carbons can be joined
If functional group present, place in different positions
Functional group isomers
Same molecular formula, different functional group
Types of bond fission
Homolytic fission
Heterocyclic fission
Homolytic fission
Each bonded atom takes one of the shared pair of electrons from bond
Each atom now has a single unpaired electron, radical
Heterolytic fission
One bonded atom takes both electrons from bond
Anions, cations formed
Reaction mechanisms
Curly arrows, heterolytic fission
Fish hook arrows, homolytic fission
Addition reactions
2 reactants join, form 1 product
Substitution reactions
Atom/groups of atoms replaced by different atoms
Elimination reactions
Removal of molecule from larger one