Acid-base Titrations Flashcards
Titration
Accurately measure volume of 1 solution that reacts exactly with another solution
Used for finding concentrations, identification of unknowns, substance purity
Volumetric flask error
100cm3
+- 0.20cm3
Volumetric flask error
250cm3
+- 0.30cm3
Pipette error
10cm3
+- 0.04cm3
Pipette error
25cm3
+- 0.06cm3
Burette error
50cm3
+- 0.10cm3
How to use burrette
Bottom of meniscus to nearest half division
Run excess solution through tap to remove air
How to use indicator
Few drops only, indicator is slightly acidic
How to use mean titres
Concordant titres 0.10 for accuracy
How to do titration calculations
Find mean titres
Stoichiometry
Concentration equation
How to work out the moles used in the titration
Multiply the moles by the scale factor of the volumetric flask volume to find the actual number of moles used in the titration
How to calculate the percentage by mass
Percentage by mass= mass of compound/ mass of total x 100
How to do back titrations
Use all information given to you
Use balanced equations
How to balance half equations in acidic conditions
Balance atoms other than H and O
Balance oxygen by adding water
Balance hydrogen by adding H+
Balance charges by adding electrons to +ve side
Combining half equations
As reduction and oxidation happen at the same time, electrons should be equal on both sides