(BLUE) Energetics 1 Flashcards

1
Q

Draw a hess cycle using letters A-Y

A

Search up Hess cycles

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2
Q

What is the study of energetics

A

The study of energy transfer between reacting chemicals and its products.

We measure the energy transfer to and from the surroundings as enthalpy change

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3
Q

What is the definition of enthalpy change for a reaction

A

: the heat change when the reaction is carried out at constant pressure pressure it gives the symbol (delta) H

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4
Q

What happens in an exothermic reaction , and what’s its symbol (+/-)

A

Energy is transferred to the surroundings , and energy levels for the compound go down so -Ve (delta) H is negative

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5
Q

What happens in an endothermic reaction and what sign(-/+)

A

Energy is transfers to the compound , therefore energy levels go up in the compound: +Ve (delta) H positive

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6
Q

Draw an enthalpy level diagram

A

Search on google

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7
Q

What is the equation of heat energy

A

Heat energy = specific heat x mass x (delta) temp (in kelvin)

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8
Q

What is the specific heat capacity of water

A

4.18 j kg-1

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9
Q

What are the units of enthalpy change

A

KJ mol-1

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10
Q

What is the definition of combustion enthalpy

A

(Delta) Hc
The heat energy when released when one mole of a substance in its standard state is completely burnt in excess oxygen understand reconditions ( 1 atm 298k)

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11
Q

What is the equation for 1 mil of (delta) H for one mole

A

(Delta)H = energy transferred / miles used

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12
Q

When carrying out combustion what else might get formed
On the tin can

A

Soot

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13
Q

List the main sources of heat loss:

A

Draughts
Heat absorbed from objects
Incomplete combustion

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14
Q

How does the number of carbons on a cain effect the enthalpy combustion

A

Would make it higher exothermic reactions
This is because more bonds are formed as more CO2 and H2O are formed

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15
Q

What is the definition of standers enthalpy change of formation

A

Enthalpy change when one mole of a substance in its standard state is formed from its elements in their standard states under standard conditions ( 1ATM 298k)

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16
Q

What is the definition of standard enthalpy change of reaction

A

The enthalpy change when molar quantities of reactants as stated in the equation react together under standard conditions (1ATM 298k 1mol dm-3)

17
Q

The standard enthalpy change of neutralisation

A

The enthalpy change of neutralisation is the enthalpy change when one mole of water is formed by the neutralisation between an acid and an alkali under standard conditions (298k 1ATM)

18
Q

How would you reduce heat loss when dealing with exo or endothermic reactions

A

Put a lid on it
Stirring
Weigh beaker before and after to measure the amount of compound used
To prevent liquids escaping from fizzing put a lid on it

19
Q

Why can’t we measure (delta) Hr of
2NaHCO2 ——> Na2CO3 +CO2 + H2O

A

Because the reaction is endothermic , and we have to beat the compound in order to react which makes it harder / impossible to measure the (delta) Hr of this reaction

20
Q

When bonds break is it exo/endo thermic

A

Endothermic

21
Q

When bonds form is it exo / Endo thermic

A

Exothermic

22
Q

What is the definition of dissociation enthalpy (also called bond enthalpy)

A

the energy required to break one mole of BONDS in a substance when it is the gaseous state

23
Q

What is the difference between :
Bond dissociation enthalpy
And
Mean bond enthalpy

A

As enthalpy can change as you keep breaking bonds in a compound , mean bond enthalpy gives you a rough average . While bond dissociation enthalpy gives you exact numbers

24
Q

Why is nitrogen (N2) Un reactive

A

Has a high bond dissociation enthalpy therefore needs a lot of energy to overcome

25
Q

Give the equation for (delta) Hr

A

(Delta) Hr = total energy to break bonds - total energy to make bonds