Blood Gas/Electrolyte Instrumentation Flashcards
That branch of electrochemistry in which a fixed charge is applied to an electrochemical cell. The charge serves as the generating or excitation signal; the response is the current measured. Molecules are oxidized or reduced at the working electrode, whose potential is controlled relative to a reference electrode such as a saturated calomel electrode or Ag/AgCl electrode.
amerperometry
an electrochemical technique related to amperometry in that a single potential is applied between two electrodes and current flows due to an oxidation or reduction reaction; all of the substance of interest is electrochemically reacted; the amount of electricity (in coulombs) produced by the process is quantitated.
coulometry
an electrochemical device that consists of two electrodes that are connected by an electroyte solution that conducts ions (galvanic cell) or a device in which an external voltage is applied to a polarizable working electrode with the resulting cathodic or anodic current of the cell being monitored
electrochemical cell
a half-cell that consists of a single metallic conductor in contact with an electrolyte solution; the indicator electrode is one half-cell and the reference electrode is the second half-cell
electrode
an electrode that selectivity interacts with a single ionic species; the potential produced at the membrane/sample solution interface is proportional to the logarithm of the ionic activity or the concentration of the ion in question
ion-selective electrode
the measurement of the potential difference between two electrodes measured at equilibrium and with no current. the potential generated is proportional to the activity (concentration) of the ion being measured.
potentiometry
the measurement of current or amperage created as the voltage applied to an electrochemical cell is changed
voltametry
describes the flow of electrons through a substance, such as a solution or a wire, and is measured in amperes, or coulombs of change per second
current
the opposition of a substance to current flow measured in ohms
resistance
properties that depend only on the NUMBER of particles in solution, not on the nature of those particles
colligative properties