bioenergetics Flashcards

1
Q

entropy symbol and definition

A

S, randomness

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2
Q

positive entropy means what

A

+S= favorable- increase in disorder

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3
Q

enthalpy symbol and definition

A

H bond energy

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4
Q

exothermic reaction delta H is what

A

negative

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5
Q

endothermic reaction delta H is what

A

positive

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6
Q

change in gibbs free energy is what

A

maximum work that a proess can perform at constant pressure and temp

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7
Q

negative delta G means

A

thermodynamically favorable and spontaneous

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8
Q

positive delta G means

A

thermodynamically unfavorable and not spontaneous

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9
Q

definition of high energy compound

A

releases more than 7 kcal/mol

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10
Q

2 classes of high energy bonds

A

thioester and high energy phosphate

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11
Q

example of thirster bond

A

C-s: acetyl CoA

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12
Q

3 examples of phosphate bonds

A

phosphoanhydride (pop like tap), phosphocreatine (PN), and phosphoenolpyruvate (COP

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13
Q

more positive the value of E means what

A

likes to attract electrons

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14
Q

the more negative the value of e means

A

likes to give up electrons

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15
Q

free energy of redox is directly related to _____________

A

the difference in reduction potential between products and reactants

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16
Q

electrons pass from compounds with ____ to _____ E and free energy is _____

A

low to high, free energy is released

17
Q

first law of thermo

A

energy is neither created nor destroyed

18
Q

second law of thermo

A

entropy of the universe is always increasing

19
Q

cutting the beta bond of ATP results in what two products

A

AMP and pyrophosphate

20
Q

positive delta G means reaction will move:

A

backwards

21
Q

negative delta G means reaction will more:

A

forwards

22
Q

when deltaG<0, the reaction is

A

spontaneous

23
Q

the deltaG>0 the reaction is

A

not spontaneous

24
Q

when deltaG=0,

A

the system is at equilibrium

25
Q

ideal state of H and S

A

-H and +S

26
Q

Kep>1 reaction moves

A

forward

27
Q

Keq<1

A

reaction moves backwards

28
Q

nucleotide=

A

base sugar and phosphate group

29
Q

nucleoside=

A

base and sugar