benzene Flashcards

1
Q

what did kekules equilibrium model of benzene show

A

that there were alternating double and single bonds in the hexagon structure of benzene

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2
Q

what were the problems with kekules equilibrium structure

A

-each functional groups bond length is different
-real benzene is more stable (lower enthalpy) than kekules benzene
-doesn’t go through an addition reaction

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3
Q

properties of benzene

A

-cyclic
-planar molecule
-C6H6
-4 valence e-
-delocalised electrons system

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4
Q

why is benzene resistant to bromination compared to alkenes

A

-in benzene electrons are delocalised
-in alkenes electrons are localised between two carbones
-benzene has a lower electron density compared to alkene having high electron density
-benzene polarises bromine less and induces a weaker dipole in bromine

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