alcohols Flashcards

1
Q

properties of alcohols

A

-high mp and bp
-soluble
-as chain increases, solubility decreases

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2
Q

why does the solubility of an alcohol decreases when chain length increases

A

as there are more Carbons compared to OH and the OH is what makes it soluble

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3
Q

what are the classifications of alcohols

A

-primary
-secondary
-tertiary

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4
Q

what is a primary alcohol

A
  • OH group is bonded to a carbon with one other alkyl groups attached
    e.g. butan-1-ol
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5
Q

what is a secondary alcohol

A
  • OH group is bonded to a carbon with two other alkyl groups attached
    e.g. propan-2-ol
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6
Q

what is a tertiary alcohol

A
  • Oh group is bonded to a carbon with three other alkyl groups attached
    e.g. 2-methyl-propan-2-ol
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7
Q

what happens during the oxidation of primary alcohols (distillation)

A

alcohol + [O] –> aldehyde + H2O

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8
Q

what happens during the oxidation of primary alcohols
(reflux)

A

alcohol + [O] –> carboxylic + H20

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9
Q

what happens during the oxidation of secondary alcohols
(distillation)

A

alcohol + [O] –> ketone + H2O

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10
Q

what happens during the oxidation of tertiary alcohols

A

tertiary alcohols cannot be oxidised

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11
Q

what is the oxidation agent used

A

acidified dichromate ions
H+/C2O7^2-

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