alcohols Flashcards
properties of alcohols
-high mp and bp
-soluble
-as chain increases, solubility decreases
why does the solubility of an alcohol decreases when chain length increases
as there are more Carbons compared to OH and the OH is what makes it soluble
what are the classifications of alcohols
-primary
-secondary
-tertiary
what is a primary alcohol
- OH group is bonded to a carbon with one other alkyl groups attached
e.g. butan-1-ol
what is a secondary alcohol
- OH group is bonded to a carbon with two other alkyl groups attached
e.g. propan-2-ol
what is a tertiary alcohol
- Oh group is bonded to a carbon with three other alkyl groups attached
e.g. 2-methyl-propan-2-ol
what happens during the oxidation of primary alcohols (distillation)
alcohol + [O] –> aldehyde + H2O
what happens during the oxidation of primary alcohols
(reflux)
alcohol + [O] –> carboxylic + H20
what happens during the oxidation of secondary alcohols
(distillation)
alcohol + [O] –> ketone + H2O
what happens during the oxidation of tertiary alcohols
tertiary alcohols cannot be oxidised
what is the oxidation agent used
acidified dichromate ions
H+/C2O7^2-