Basics Flashcards

1
Q

What is metabolism?

A

the sum of all chemical reactions occurring in a living organism

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2
Q

Chemical reactions in cells

A

-Involve energy changes
-catalyzed by enzymes
-enzymes attempt to drive the reaction toward equilibrium
-as enzyme-catalyzed reactions proceed toward equilibrium they release energy

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3
Q

Bioenergetics

A

chemical thermodynamics as it applies to living organisms (energy changes in chemical systems)

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4
Q

How is energy used in living organisms?

A

-Anabolism
-Muscle contraction
-Transport Process
-Control mechanisms

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5
Q

What are the laws of thermodynamics?

A

First: in any physical or chemical change, the total amount of energy in the universe remains constant, although the form of energy may change

Second: in all natural processes, the entropy of the universe increases

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6
Q

Delta H

A

Enthalpy change: change in form, reactants to products, endothermic/exothermic

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7
Q

Exothermic reaction

A

heat energy is given off, energy released (-delta H)

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8
Q

Endothermic reaction

A

requires energetic input, (+delta H)

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9
Q

Entropy Change

A

Increase in the randomness or disorder within a system (Delta S)

measure of energy dispersal, diffusion of energy when randomness increases delta S is positive.

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10
Q

First Law of Thermodynamics

A

in any physical or chemical change, the total amount of energy in the universe remains constant although the form of the energy may change

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11
Q

Second law of thermodynamics

A

in all natural processes,the entropy of the universe increases
-teakettle, oxidation of glucose

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12
Q

Delta G

A

Free energy change:L the maximum energy available from a reaction or process that can be harnessed to do something useful.

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13
Q

Exergonic Reaction

A

free energy released
spontaneous
favorable reaction
can occur by itself
-delta G

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14
Q

Endergonic Reaction

A

Energy is required
not spontaneous
not favorable
can’t occur by itself

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15
Q

Free Energy Change Equation

A

Delta G= Delta H - T(Delta S)
enthalpy change -temperature (kelvin) times entropy change

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16
Q

Delta G > 0

A

free energy of the product is higher than free energy of the reactants (endergonic)

17
Q

Delta G < 0

A

Free energy of the products is lower than the free energy of the reactants (exergonic)

18
Q

Delta G = 0

A

No free energy change, state of dynamic equilibrium

19
Q

Stanard free energy change equation

A

Delta G= Delta G^’ + RT ln ([C][D]/[A][B])

Delta G^’= standard free energy change (1.0M, 25C,pH 7.0)
R= gas constant (8.315J/mol)
T= absolute temperature (K)
ln= natural log

20
Q

Keq

A

= 1 at equilibrium

Equilibrium Constant: (Reactants/Products)

21
Q

PCr

A

Creatine Phosphate:

22
Q

ATP

A

Adenosine Triphosphate
Nitrogenous Adenine Base
5 carbon ribose (beta deoxyribose)
three phosphryl groups

Hydrolysis of phosphoanyhidride linkages releases a lot of energy, can be hydrolized at either but not simultaneously

Hydrolysis between Beta and y group is more common

23
Q

Which molecule is represented here?

A

ATP

24
Q

Hydrolysis of ATP (between beta and y phosphoryl groups)

A

atp+h20 <> ADP +Pi + H+

1 atp + 1 water = adp, inorganic phosphate and a hydrogen ion

25
Q

Hydrolysis of ATP (between alpha and beta phosphoryl groups)

A

AMP + PPI

Adenosine monophosphate and inorganic pyrophosphate