Atomic Physics Flashcards

1
Q

3-D time independent Schrödinger equation

A
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2
Q

General Schrödinger Equation

A
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3
Q

Cubical box energy levels

A
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4
Q

Magnitude of orbital angular momentum

A
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5
Q

Z component of orbital angular momentum

A
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6
Q

Zeeman effect (qualitative description)

A

When an external magnetic field is applied, sharp spectral lines split into multiple closely spaced lines.

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7
Q

Bohr magneton

A
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8
Q

Magnitude of spin angular momentum

A
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9
Q

Spin magnetic quantum number

A
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10
Q

Pauli exclusion principle

A

In any given quantum system, no two fermions can occupy identical quantum states.

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11
Q

What causes optical spectra and what causes characteristic x-rays?

A

Characteristic x-rays are emitted when outer-shell electrons fill a vacancy in the inner shell of an atom. Optical spectra are caused by transitions of outer electrons.

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12
Q

Electron transition selection rules

A
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13
Q

Angular momentum in the Bohr model

A
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14
Q

Hamiltonian responsible for the Zeeman effect

A
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15
Q

Stark effect (qualitative)

A

The splitting of degenerate energy levels into closely spaced multiplets under the application of an external electric field. Note that it causes no change in the ground state energy of a hydrogenic atom to first order in the electric field magnitude.

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16
Q

Chemistry naming of orbitals

A

l = 0, 1, 2, 3 for s, p, d, f

17
Q

What are the allowed values for n, l, m?

A

n = 1, 2, 3, 4, ….

l = 0, 1, 2, …, n-1

m = -l, -l+1,…, 0, … l-1, l

18
Q

How many allowed states are there per orbital in atoms?

A

2(2l+1)

19
Q

Stefan-Boltzmann law

A

(for black-bodies)

20
Q

Wien’s displacement law

A

(for black-bodies)

21
Q

X-ray K lines energies

A
22
Q

Spectroscopic notation

A

(L = S, P, D, F, …)

23
Q

Lyman and Balmer series

A

Lyman refers to transitions in hydrogen to the n = 1 state, while Balmer refers to transitions (down) in hydrogen to the n = 2 state.

24
Q

Energy of hydroen-like systems

A
25
Q

Proportionalities of fine structure perturbations to hydrogenic atoms

A
26
Q

Proportionalities of Lamb shift perturbations to hydrogenic atoms

A
27
Q

Proportionalities of hyperfine / spin-spin perturbations to hydrogenic atoms

A