Atomic orbitals Flashcards

1
Q

What are wavefunctions?

A

Mathematical equations of a position in space that describe the wave-behaviour of electrons

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2
Q

What equation is used to calculate wavefunctions?

A

Schrodinger equation

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3
Q

What is Ψ² ?

A

The probability of finding an electron at a given location is proportional to the square of the wavefunction at that point

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4
Q

What are the three requirements of wavefunctions?

A

Finite
Single-valued
Continuous

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5
Q

What does finite mean?

A

There is 100% chance of finding an electron in the atom

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6
Q

What does single-valued mean ?

A

There can only be 1 probability value of finding an electron at a certain point

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7
Q

What are the two components to wavefunctions?

A

Radial component R (r)

Angular component A (θ, ω)

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8
Q

What happens to the value of the wavefunction as the distance from the nucleus increases?

A

Approaches to zero

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9
Q

What are the three types of boundary conditions in the hydrogen atom?

A
  1. radial

2. 3. angular

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10
Q

Will you find electrons at a node?

A

No

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11
Q

What do the three boundary conditions produce?

A

3 quantum numbers

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12
Q

What two types of nodes are produced from the three boundary conditions?

A

Radial nodes

Angular nodes

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13
Q

What are radial nodes?

A

determine the effective size

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14
Q

What are angular nodes?

A

determine the shape

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15
Q

The higher the number of nodes…

A

The higher the energy

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16
Q

What are the three types of quantum number?

A

n
ι

17
Q

What does n stand for in terms of quantum number?

A

Principle quantum number

18
Q

What does ι stand for in terms of quantum number?

A

Angular momentum quantum number

19
Q

What does Mι stand for in terms of quantum number?

A

Magnetic quantum number

20
Q

What does n specify?

A

Total number of nodes in an orbital

21
Q

How do you calculate the total number of nodes?

A

n - 1

22
Q

What does ι specify?

A

the number of angular nodes in an orbital and describes the shape of the orbital

23
Q

What type of value can ι have?

A

Integer value between 0 and n-1

24
Q

What can the value of angular nodes not be higher than?

A

total nodes

25
Q

What is Mι?

A

The number of different orbitals that have the same values of n and ι, describes the orientation

26
Q

What values can Mι have if ι is 0?

A

Only 0

27
Q

What values can Mι have if ι is 1?

A

-1, 0, 1

28
Q

What values can Mι have if ι is 2?

A

-2, -1, 0, +1, +2

29
Q

What is n given as?

A

Numbers

30
Q

What is ι given as?

A

Letters

31
Q

What is Mι given as?

A

Mathematical function

eg, xy, xz

32
Q

What is the shape of the 1s orbital?

A

Spherically symmetrical and has no nodes

33
Q

What is the shape of the 2s orbital?

A

One radial node and spherically symmetrical

34
Q

What is the shape of the 3s orbital?

A

Two radial nodes and spherically symmetrical