AS: Shapes Of Molecules Flashcards

1
Q

Bond Angle: NO lone pairs?

A

109.5

E.g. NH4+

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2
Q

Bond Angle: 1 LONE PAIR?

A

107 degrees

E.g. NH3

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3
Q

Bond Angles: 2 LONE PAIRS and EXAMPLE?

A

104.5 degrees

E.g. Water

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4
Q

Name: 2 electron pairs on Central Atom and example

A

Linear

180 degrees

BeCl2

MS: 2 BONDS REPEL EQUALLY

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5
Q

Name: 3 electron pairs on Central Atom

A

No LONE pairs: BF3 : Trigonal Planar

1 LONE pair: SO2 : Non-Linear/Bent

                  120 degrees
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6
Q

Name: 4 electron pairs on Central Atom

A

No LONE pairs: NH4+ : Tetrahedral

1 LONE pair: Trigonal Pyramidal

2 LONE pairs: Non-Linear/Bent

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7
Q

Name: 5 electron pairs on Central Atom

A

No LONE pairs: PCl5 : Trigonal bipyramidal

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8
Q

Name: 6 electron pairs on Central Atom

A

No LONE pairs: SF6 : Octahedral

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9
Q

Describe the Valence-Shell Electron-Pair Repulsion Theory

A

1) LP - LP = bond angles BIGGEST
2) LP - BP = bond angles 2nd BIGgest
3) BP - BP = bond angles smallest

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10
Q

Degrees: Trigonal Planar?

And, with a lone pair?

A

120 degrees because the EXTRA ELECTRON DENSITY cancels out EXTRA REPULSION from the lone pair

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11
Q

Degrees: Tetrahedral

1 LONE PAIR
2 LONE PAIRS

A

109.5
107
104.5

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12
Q

Degrees: Trigonal BiPyramidal?

A

90 between Cl

120 between wedge & dotted

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13
Q

Degrees: Octahedral?

A

90 degrees

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14
Q

Why does TlCl2 + ion have a linear shape?

A

two bonds (PAIRS of ELECTRONS) repel EQUALLY

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