AS: Shapes Of Molecules Flashcards
Bond Angle: NO lone pairs?
109.5
E.g. NH4+
Bond Angle: 1 LONE PAIR?
107 degrees
E.g. NH3
Bond Angles: 2 LONE PAIRS and EXAMPLE?
104.5 degrees
E.g. Water
Name: 2 electron pairs on Central Atom and example
Linear
180 degrees
BeCl2
MS: 2 BONDS REPEL EQUALLY
Name: 3 electron pairs on Central Atom
No LONE pairs: BF3 : Trigonal Planar
1 LONE pair: SO2 : Non-Linear/Bent
120 degrees
Name: 4 electron pairs on Central Atom
No LONE pairs: NH4+ : Tetrahedral
1 LONE pair: Trigonal Pyramidal
2 LONE pairs: Non-Linear/Bent
Name: 5 electron pairs on Central Atom
No LONE pairs: PCl5 : Trigonal bipyramidal
Name: 6 electron pairs on Central Atom
No LONE pairs: SF6 : Octahedral
Describe the Valence-Shell Electron-Pair Repulsion Theory
1) LP - LP = bond angles BIGGEST
2) LP - BP = bond angles 2nd BIGgest
3) BP - BP = bond angles smallest
Degrees: Trigonal Planar?
And, with a lone pair?
120 degrees because the EXTRA ELECTRON DENSITY cancels out EXTRA REPULSION from the lone pair
Degrees: Tetrahedral
1 LONE PAIR
2 LONE PAIRS
109.5
107
104.5
Degrees: Trigonal BiPyramidal?
90 between Cl
120 between wedge & dotted
Degrees: Octahedral?
90 degrees
Why does TlCl2 + ion have a linear shape?
two bonds (PAIRS of ELECTRONS) repel EQUALLY