AS: Metallic Bonding Flashcards
What is delocalised and what is the product of this?
The OUTERMOST shell of ELECTRONS of a metal ATOM are DELOCALISED - electrons free to move about the metal
• leaves a + metal ION
Metal elements exist as…
GIANT METALLIC LATTICE STRUCTURES
Describe Metallic Bonding
the + metal IONS ❤️ attracted to the DELOCALISED NEGATIVE ELECTRONS. Forms LATTICE of CLOSELY PACKED IONS in a sea of DELOCALISED ELECTRONS
Why does Mg2+ have a HIGHER MP than Na+?
Mg2+ has 2 delocalised electrons PER ATOM wheras Na+ only has 1
• more delocalised electrons, the STRONGER the BONDING so the HIGHER the MP
Why are metals “Malleable”?
((can be shaped))
• NO bonds holding specific IONS together so the metal IONS can slide over each other when structure is pulled
What does the term “ductile” mean?
can be drawn into a WIRE
Why are metals GOOD THERMAL CONDUCTORS?
cos the DELOCALISED ELECTRONS can pass KINITIC ENERGY to each other
Are metals soluble or insoluble?
INSOLUBLE cos of the strength of metallic bonds
(except in LIQUID METALS)
Describe the physical properties of a SOLID:
PARTICLES
- particles very close together
- high density
- making it INCOMPRESSIBLE
- particles VIBRATE about a FIXED POINT - can’t move freely
Describe the physical properties of a LIQUID:
PARTICLES
- SIMILAR density to a solid
- VIRTUALLY incompressible
- particles move about freely + RANDOMLY within liquid, allowing it to FLOW
Describe the physical properties of a GAS:
PARTICLES
- particles have MORE ENERGY & FURTHER APART
- Low Density
- VERY compressible
- particles move freely
What do the physical properties of a SOLID DEPEND on?
(3 points)
- MP + BP depend on ATTRACTION ❤️ BETWEEN PARTICLES
- the CLOSER the particles, the GREATER the DENSITY
- If CHARGED particles are FREE to MOVE - electricity conducted ✅
What do the physical properties of a SOLID DEPEND on?
(2 points)
- SOLUBILITY depends on the TYPE of particles present
* If a solid has a REGULAR structure, it’s called a CRYSTAL. Structure is a CRYSTAL LATTICE
Give one limitation of a model of BONDING:
Most bonds AREN’T purely IONIC/COVALENT but somewhere in between. Due to BOND POLARISATION.
DOT + CROSS MODELS ❌