AS: Chemistry 2: Organic Flashcards
General formula of CARBONYL compounds?
Cn H2n O
Secondary Alcohols are oxidised to…?
and how you gon get that?
KETONES
REFLUX 2• alcohol with
ACIDIFIED potassium dichromate (VI)
Primary Alcohols are oxidised to?
and how you gonna get that?
ALDEHYDES ➡️ CARBOXYLIC ACIDS
- HEATING
- POTASSIUM DICHROMATE (VI)
- and SULFURIC ACID
Test to distinguish between Aldehyde and Ketone?
Tollen’s
TOLLEN’s reagent
- Silver Mirror ~ ALDEHYDE
- No Change ~ KETONE
Test to distinguish between Aldehyde and Ketone?
Benedict’s
Benedict’s solution
- Brick Red ppt ~ ALDEHYDE
- No Change ~ KETONE
Conditions needed for Elimination?
- ETHANOLIC SOLVENT
- ⬆️ conc. of OH-
- ⬆️ Temperature ???
How many arrows in Eli min at ion
3
How many arrows in Nucleophilic Sub?
2
What happens if a TERTIARY ALCOHOL reacts with POTASSIUM DICHROMATE (VI)
• NOTHING ?
Solution stays ? ORANGE
How CAN you oxidise a TERTIARY alcohol?
Burning it ?
To get JUST an Aldehyde, and not a Carboxyl Acid, what do you do?
heat EXCESS ALCOHOL with a CONTROLLED amount of o❌idising agent in DISTILLED APPARATUS so the aldehyde (boils at lower temp than ALCOHOL)
is DISTILLED OFF IMMEDIATELY‼️
Primary Alcohol + Potassium DICHROMATE (VI) =
and what colour?
Aldehyde and Carboxylic Acid
ORANGE - GREEN
Addition Polymers are formed from?
Alkenes
Condensation Polymers are made from?
Two different monomers AND EACH monomer has at least 2 functional groups
How are PolyAMIDES made?
dicarboxylic acids and diamines form amide links