AS: Chemistry 2: Organic Flashcards

1
Q

General formula of CARBONYL compounds?

A

Cn H2n O

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2
Q

Secondary Alcohols are oxidised to…?

and how you gon get that?

A

KETONES

REFLUX 2• alcohol with
ACIDIFIED potassium dichromate (VI)

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3
Q

Primary Alcohols are oxidised to?

and how you gonna get that?

A

ALDEHYDES ➡️ CARBOXYLIC ACIDS

  • HEATING
  • POTASSIUM DICHROMATE (VI)
  • and SULFURIC ACID
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4
Q

Test to distinguish between Aldehyde and Ketone?

Tollen’s

A

TOLLEN’s reagent

  • Silver Mirror ~ ALDEHYDE
  • No Change ~ KETONE
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5
Q

Test to distinguish between Aldehyde and Ketone?

Benedict’s

A

Benedict’s solution

  • Brick Red ppt ~ ALDEHYDE
  • No Change ~ KETONE
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6
Q

Conditions needed for Elimination?

A
  • ETHANOLIC SOLVENT
  • ⬆️ conc. of OH-
  • ⬆️ Temperature ???
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7
Q

How many arrows in Eli min at ion

A

3

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8
Q

How many arrows in Nucleophilic Sub?

A

2

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9
Q

What happens if a TERTIARY ALCOHOL reacts with POTASSIUM DICHROMATE (VI)

A

• NOTHING ?

Solution stays ? ORANGE

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10
Q

How CAN you oxidise a TERTIARY alcohol?

A

Burning it ?

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11
Q

To get JUST an Aldehyde, and not a Carboxyl Acid, what do you do?

A

heat EXCESS ALCOHOL with a CONTROLLED amount of o❌idising agent in DISTILLED APPARATUS so the aldehyde (boils at lower temp than ALCOHOL)
is DISTILLED OFF IMMEDIATELY‼️

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12
Q

Primary Alcohol + Potassium DICHROMATE (VI) =

and what colour?

A

Aldehyde and Carboxylic Acid

ORANGE - GREEN

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13
Q

Addition Polymers are formed from?

A

Alkenes

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14
Q

Condensation Polymers are made from?

A

Two different monomers AND EACH monomer has at least 2 functional groups

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15
Q

How are PolyAMIDES made?

A

dicarboxylic acids and diamines form amide links

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