APES Unit 9 Flashcards
What radiation does stratospheric ozone absorb?
UV-C and most UV-B radiation.
Why is the ozone layer crucial for life on Earth?
It prevents harmful UV-B and UV-C radiation, which damage tissues and mutate DNA.
Health benefits of stratospheric ozone?
Prevents skin cancer and cataracts.
What is tropospheric ozone?
A respiratory irritant and plant toxin; contributes to photochemical smog.
How does ozone absorb UV-B and UV-C?
UV-C splits O₂ → O + O. Free O + O₂ → O₃. UV-C also breaks O₃ → O₂ + O.
What is the anthropogenic cause of ozone depletion?
CFCs from aerosols and refrigerants.
How do CFCs destroy ozone?
UV frees Cl from CFCs → Cl reacts with O₃ → O₂ + ClO → Cl continues cycle.
How long can 1 Cl atom destroy ozone?
50–100 years; up to 100,000 molecules.
Natural ozone depletion source?
Polar Stratospheric Clouds (PSC) in Antarctic spring form CI₂ → UV splits into 2 Cl atoms.
Main way to reduce ozone depletion?
Phase out and replace CFCs.
What is the Montreal Protocol (1987)?
Global agreement to ban CFCs in aerosols, fridges, etc.
What replaced CFCs?
HCFCs (temporary) → less harmful than CFCs, but still deplete ozone.
What replaced HCFCs?
HFCs – don’t contain Cl, so don’t deplete ozone, but still GHGs.
What’s the best current replacement?
HFOs – HFCs with C=C bonds → shorter lifetime and lower global warming potential (GWP).
How much solar radiation is reflected by clouds/atmosphere?
0.26
How much is absorbed by atmosphere/clouds?
0.19
What is albedo?
The ability of a surface to reflect sunlight. Dark = low, light = high.
How does the greenhouse effect work?
Earth absorbs solar radiation → emits IR → GHGs trap IR → radiate back to Earth.
Important greenhouse gases (GHGs)?
CO₂, CH₄, N₂O, CFCs, HCFCs, HFCs, water vapor (H₂O).
What is Global Warming Potential (GWP)?
How much a gas contributes to warming compared to CO₂ over 100 years.
GWP comparisons:
CH₄: higher IR absorption, lasts 12 years.
N₂O: lasts 115 years, strong IR absorption.
CFCs: 50–500 years, very high IR absorption.
CO₂: baseline GWP = 1.
Why is sea level rising?
Thermal expansion and melting of land-based ice (glaciers and ice sheets).
What doesn’t cause sea level rise?
Sea ice (e.g., North Pole ice).
Environmental effects of sea level rise?
Flooded estuaries, loss of polar ecosystems, disrupted freshwater from glaciers.