Ap Chem. Ch.5 Flashcards

0
Q

The study of the relationships between chemical reactions and energy changes involving heat.

A

Thermochemistry

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1
Q

The study of energy and its transformations

A

Thermodynamics

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2
Q

Ability to work or transfer heat.

A

Energy

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3
Q

Energy used to cause and object that has mass to move.

A

Work

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4
Q

Energy used to cause the temperature of an object to rise.

A

Heat

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5
Q

Energy of motion

A

Kinetic energy

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6
Q

Equation for kinetic energy

A

E = 1/2mv^2

k

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7
Q

Energy an object possesses by virtue of its position or chemical composition.

A

Potential enery

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8
Q

Joule actually equals…

A

1 kg(m^2)/s^2

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9
Q

Work equation

A

F x d

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10
Q

The energy transfered from a hotter object to a colder one.

  • deals with the motion of objects
  • always flows from hot to cold objects
A

Heat

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11
Q

States that energy cannot be created or destroyed.

A

The first law of thermodynamics

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12
Q

The total energy of a system

A

Internal energy

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13
Q

Changes in internal energy can be measured using this equation.

A

/_\ E= Ef-Ei

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14
Q

When a system undergoes a physival or chemical change, the change in internal energy is given by the heat added or liberated from the system plus the work done on or by the system. What is the equation?

A

/_\E= q +w

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15
Q

An endothermic process is one that ________ heat from the surroundings.

A

Absorbs

16
Q

An exothermi processs is one that ______heat to the surroundings.

A

Releases

17
Q

Depends only on the initial and final states of a system, not by the path by which the system arrived at that state.

A

A state function

18
Q

P,V,T,E,H are state fuctions.

A
Pressure
Volume
Temperature
Internal energy
Heat changes at constant pressure
19
Q

Chemical changes may involve…

-may also involve work done on or by the system

A

Release of absorption of heat

20
Q

The heat transfered between the system and surroundings during a chemical reaction carried out under constant pressure.

A

Enthalpy

21
Q

The enthalpy change that accompanies a reation is called…

A

Enthalpy of reaction

22
Q

Balanced chemical equation that includes states and energy

A

Thermochemical equation

23
Q

Enthalpy is an ______ property

A

Extensive

24
Q

The /_\ H of enthalpy is _______proportional to the amount of reactant consumed.

A

Directly

25
Q

Measurment of heat flow.

A

Calorimetry

26
Q

Is an apparatus that measures heat flow.

A

Calorimeter

27
Q

The amount of energy required to raise the temperature of an object by 1 degree celsius.

A

Heat capacity

28
Q

The heat capacity of 1 g of a substance.

A

Specific heat

29
Q

Equation for heat capacity

A

q=m x c x /_\T

30
Q

Calculations with constant-pressure calorimetry

A

m(solution) x c(solution) x /_\T (solution)= - qrxn

31
Q

If a reaction is carried out in a series of steps, /\H for the reaction is the SUM of /\H for each of the steps.

A

Hess’s Law