alkenes Flashcards

1
Q

why is there no rotation around the C=C bond

A

due to the pi bond, the double bond is an electron dense region to hold the carbon atoms in place

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2
Q

what is an electrophile

A

electron pair acceptor

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3
Q

description of the reaction between bromine and alkene

A

reagent: bromine
condition: room temp
mechinism: electrophillic addition

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4
Q

what is the test for unsaturation

A

add bromine water, observe colour change from orange to colourless

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5
Q

properties of poly(ethene)

A

layers can pack closely together, has strong IM forces and therefore a stronger and more rigid material

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6
Q

properties of poly(phenylethene)

A

has a large phenyl branch which disrupts the IM forces, layers cant pack closely together making it more flexible

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7
Q

use of pvc

A

drainpipes, vinyl and aprons

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8
Q

use of pvc with plasticiser

A

electrical cable insulation flooring tiles and clothing

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9
Q

how can alkenes from addition polymers

A

the C=C double bond breaks open

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10
Q

why is a secondary carbocation more stable than a primary carbocation

A

secondary carbocations have more alkyl groups which have a positive inductive effect and push the electrons onto the C+ making it more stable

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11
Q

what is plasticiser

A

it is added to make a polymer more flexible by reducing IM forces so chains can move around more

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12
Q

what is the difference between saturated and unsaturated

A

saturated: only having single carbon bonds
unsaturated: having double bonds aswell as single

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13
Q

addition polymers

A

formed from alkenes
they are unreactive
ethene -> poly(ethene)
represented with brackets with visible broken bonds

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