alkanes Flashcards

1
Q

what is cracking and why is it done

A

breaking of C-C bonds in long chain hydrocarbons into smaller chain hydrocarbons as shorter chains are more valuable

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2
Q

what are the conditions and products for thermal cracking

A

high temp - 1000 degrees C
high pressure - 70ATM
produces short chain alkenes

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3
Q

what are the conditions and products for catalytic cracking

A

lower temp - 500 degrees C
slight pressure
zeolite catalyst
aromatic compounds

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4
Q

equation for catalytic converters

A

2NO –> N2 + O2

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5
Q

how is a catalytic converter efficient at its job

A

it has a honeycomb structure to maximise surface area

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6
Q

what happens when sulfur impurities are burnt

A

sulfur will dissolve in the air and fall down as acid rain which kills trees and harms aquatic animals

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7
Q

how is SO2 removed from the atmosphere + equation

A

CaO removes SO2 from flue gases forming CaO3
CaO + SO2 –> CaO3

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8
Q

how does CO2 contribute to global warming

A

CO2 absorbs infrared radiation which emmits the energy back into the atmoshphere increasing the temp

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9
Q

equation for methane + chlorine

A

CH4 + Cl2 –> CH3Cl + HCl

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10
Q

initiation step for chlorination of an alkane

A

Cl2 -> 2Cl.

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11
Q

2 propagation steps for the chlorination of methane

A

.Cl + CH4 –> .CH3 + HCl
.CH3 + Cl2 –> CH3Cl + Cl.

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12
Q

3 termination steps for the chlorination of methane

A

.Cl + .Cl -> Cl2
.Cl + .CH3 -> CH3Cl
.CH3 + .CH3 -> C2H6

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13
Q

how is crude oil seperated

A
  1. oil is heated and passed through the column as a vapour
  2. the fractions will condense at different heights of the column as temperature decreases as you go up the column
  3. at which fraction the vapour condenses at is dependent on the boiling point of the fraction
    4.smaller molecules condense at the top of the fraction due to weak van der waal forces.
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14
Q

equation for combustion of methane

A

CH4 + O2
–> CO2 + H2O

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15
Q

equation for incomplete combustion

A

CH4 + O2 –> C + 2 H2O

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16
Q

environmental consequence of Nitrogen oxides

A

NO is toxic and can form NO2
NO2 is toxic and forms acid rain

17
Q

environmental consequence of carbon monoxide

A

toxic -> respiratory problems

18
Q

env

A
19
Q

environmental consequence of carbon dioxide

A

adds to global warming

20
Q

environmental consequence of unburnt hydrocarbons

A

adds to the formation of smog

21
Q

environmental consequence of soot

A

global dimming and respiratory problems

22
Q

how is free radical substitution a chain reaction

A

a chlorine radical is regenerated which can react with more methane molecules to continue the reaction