optical isomerism Flashcards
stereoisomersim
the same structural formula but different spatial arrangement
optical isomerism
occurs in carbon compounds with 4 different groups of atoms attached
what is a chiral carbon
the carbon atom with 4 different groups attached
enantiomers
two compounds which are optical isomers
how are enantiomers similar and different
they have similar physical and chemical properties but they rotate plane polarised light in different directions but by the same amount. one enantiomer rotates clockwise, and the other rotates anti clockwise.
what is plane polarised ligtht
light which oscillates in one direction
racemic mixtures
a mixture of equal amounts of both optical isomers. the mixture will not rotate plane polarised light.
formation of a racemic mixture
forms when a reactant or an intermediate has a trigonal planar group and is approached from both sides by a species.
why are racemic mixtures optically inactive
both enantiomers will rotate in equal amounts and cancel the rotations out