optical isomerism Flashcards

1
Q

stereoisomersim

A

the same structural formula but different spatial arrangement

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2
Q

optical isomerism

A

occurs in carbon compounds with 4 different groups of atoms attached

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3
Q

what is a chiral carbon

A

the carbon atom with 4 different groups attached

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4
Q

enantiomers

A

two compounds which are optical isomers

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5
Q

how are enantiomers similar and different

A

they have similar physical and chemical properties but they rotate plane polarised light in different directions but by the same amount. one enantiomer rotates clockwise, and the other rotates anti clockwise.

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6
Q

what is plane polarised ligtht

A

light which oscillates in one direction

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7
Q

racemic mixtures

A

a mixture of equal amounts of both optical isomers. the mixture will not rotate plane polarised light.

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8
Q

formation of a racemic mixture

A

forms when a reactant or an intermediate has a trigonal planar group and is approached from both sides by a species.

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9
Q

why are racemic mixtures optically inactive

A

both enantiomers will rotate in equal amounts and cancel the rotations out

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