Alkanes Flashcards
straight-chain alkanes
eg butane CnH2n+2
branch chain alkanes
eg methyl butane CnH2n+2
cycloalkanes
eg cyclohexane CnH2n
naming alkanes
C atoms are numbered to give the smallest number to the branch chains and in alphabetical order.
melting point and boiling point of straight-chain alkanes
increase as the length of the carbon chain increases because the longer (larger) the molecule, the stronger the forces of attraction are between those molecules.
solubility of alkanes in water and other polar solvents
insoluble because alkane molecules are all non-polar (float on water because they have a lower density)
solubility of alkanes in other alkanes (or other hydrocarbons)
soluble because these molecules are also non-polar and will dissolve non-polar molecules.
substitution reaction
one atom (or group of atoms) is replaced by another atom (or group of atoms)
substitution equation
alkane + halogen arrow (UV light) haloalkane + hydrogen halide
C2H6 + Br2 arrow (UV light) bromoethane + HBr (hydrogen bromide)
substitution reaction example
ethane + bromine arrow (UV light) bromoethane + hydrogen bromide