ALKALIMETRY Flashcards

1
Q

The strength of an acid
solution is determined by
titrating it against a standard
base solution or determining the
strength of an alkali solution by
titration with a standard acid
solution.

A

Principle of Acid – Base
Titration

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2
Q

is used to monitor
the reaction

A

pH indicator

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3
Q

reaction
usually occurs between acid and
base, hydroxide ions and hydrogen
protons, resulting in the formation
of water

A

neutralization

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4
Q

re chemical processes
whereby an amount of an acid has reacted with
an equivalent amount of a base with the
production of salt and water.

A

Neutralization reactions

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5
Q

is the measurement of basic
substances by titration with
a standard acid

A

ACIDIMETRY

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6
Q

involves the determination
of acidic substances by
titration with a standard
base solution.

A

ALKALIMETRY

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7
Q

any substance which releases H ions in water solution

A

ARRHENIUS ACID

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8
Q

any substance which releases OH ions in water solution

A

ARRHENIUS BASE

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9
Q

any substance which donates a proton

A

BRONSTED LOWRY ACID

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10
Q

any substance which accepts a proton

A

BRONSTED LOWRY BASE

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11
Q

any substance which can accept an electron pair

A

LEWIS ACID

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12
Q

any substance which can donate an electron pair

A

LEWIS BASE

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13
Q

is any substance which in water ionizes to give hydrogen ions
(hydronium ions*)

A

ACID

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14
Q

is any substance which in water ionizes to give hydroxyl ions

A

BASE

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15
Q

is the combination of the proton and hydroxyl ion to
form the water molecule.

A

NEUTRALIZATION

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16
Q

by-product of neutralization

A

SALT

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17
Q

NEUTRALIZATION
Based on Media (Solvent) Used

A

Aqueous titrimetry
Non-aqueous titrimetry

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18
Q

use water as the solvent for
dissolving the analyte samples for the
titration.

A

Aqueous titrimetry

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19
Q

the concept of acids and bases has been
extended to include solvents other than
water, acids other than proton donors, and
bases other than hydroxyl ions donors.
These are considered, on nonaqueous
titrimetry

A

Non-aqueous titrimetry

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20
Q

Non-aqueous titrimetry use ______ for dissolving the
sample.

A

organic solvents

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21
Q

Strong Acid + Strong Base

A

Phenolphthalein, methyl red, methyl orange

22
Q

Weak Acid + Strong Base

A

Phenolphthalein

23
Q

Weak Acid + Weak Base

A

No indicator

24
Q

Strong Acid + Weak Base

A

Methyl red

25
Q

Weak Base + Salt

A

Crystal violet, Quinaldine red, malachite green

26
Q

Relatively Strong Base

A

Methyl red, methyl orange

27
Q

Weak acid

A

Azo-violet, o-nitro-aniline (very WA)

28
Q

Strong Acid

A

Thymol blue

29
Q

BASES’ BURETTE

A

MOHR’S BURETTE

30
Q

ACIDS BURETTE

A

GEISSLER’S BURETTE

31
Q

The most common application of acid-base
titrations is

A

determining an unknown analyte’s acid
or base concentration

32
Q

_______ is carried out with ACID-BASE TITRIMETRY

A

Quantitative chemical analysis

33
Q

Pharmaceutical applications of Acid-Base
Titrimetry

A

A barbiturate, aspirin, and amino acid

34
Q

An environmental analysis can be conducted with
it.

A

Application of Acid-Base
Titrimetry

35
Q

percentage potency, strength or
percentage purity of a drug or preparation.
- amount per 100

A

% assay

36
Q

Types of Titration Based On The
Number of Volumetric Solution

A

DIRECT AND RESIDUAL/BACK TITRATION

37
Q

Titrant is added into the analyte until chemical
equivalent amounts of them reacts together

A

DIRECT

38
Q

Described as the amount of
volumetric solution in excess. The excess is back titrated with
another volumetric solution

A

RESIDUAL OR BACK TITRATION

39
Q

ONLY 1 VOLUMETRIC SOLN/STD. SOLUTION

A

DIRECT

40
Q

USES 2 VOLUMETRIC SOLN. (VISS)
1 or more std. sol’n., involve addition of excess std. sol’n. & the
excess is back titrated w/ another std. sol’n

A

RESIDUAL

41
Q

WHY Residual Titration?

A

❖ Volatile
❖ Sample is insoluble in water
❖ Reaction with standard solution is
slow
❖ Sample does not give a distinct
endpoint with an indicator by
direct titration (No sharp
endpoint)

42
Q

can be calculated by dividing the mass
of the pure chemical by the total mass of the sample, and then multiplying
this number by 100.

A

Percentage Purity

43
Q

s carried in the same manner as
the actual test BUT without the sample

A

Blank test

44
Q

Blank test are Performed to correct errors due to

A
  • the presence of impurities in the reagents
  • changes in volume at different temperature
  • absorption of carbon dioxide by the alkali
  • by the alkalinity imparted by the glass
45
Q

ml in the blank titration is ml of acid =

A

total base

46
Q

ml in actual is ml of acid =

A

base found in excess

47
Q

l of acid that reacted with sample =

A

ml of
the base that reacted with the sample

48
Q

is the analysis of an acid , acid
salt or other acidic substance

A

Alkalimetry

49
Q

f using an accurately measured volume
of a standard alkali solutions

A

DIRECT

50
Q

if the process requires adding an
excess of the standard alkali solution and
determining the amount in excess by residual
titration with standard acid solution

A

RESIDUAL