ACIDIMETRY Flashcards

1
Q

Is the analysis of a base using an
accurately measured volume of standard acid
solution

A

Acidimetry

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2
Q

if using an accurately measured volume of a standard acid solution

A

DIRECT

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3
Q

If the process requires adding an excess
of the standard acid solution and determining the
amount in excess by residual titration with
standard alkali solution

A

RESIDUAL

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4
Q

What kind of assay is Assay of Sodium Bicarbonate

A

DIRECT ACIDIMETRIC ASSAY

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5
Q

Assay of Sodium Bicarbonate

A
  1. 3 g of NaHCO3 dissolved in 25 ml of water
  2. Add the indicator
  3. Titrate with 1 N Sulfuric
    acid
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6
Q

mEq of NaHCO3

A

0.084

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7
Q

What kind of assay is Assay of Zinc Oxide

A

RESIDUAL ACIDIMETRIC ASSAY

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8
Q

Assay of Zinc Oxide

A
  1. accurately weighed sample of zinc oxide
  2. add ammonium chloride
  3. dissolved in 50 mL of 1-N sulfuric acid
  4. Indicator is added
  5. excess acid is titrated with sodium hydroxide until the endpoint is reached.
  6. Calculate the
    percentage
    purity of zinc
    oxide.
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9
Q

mEq of ZnO

A

0.0407

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10
Q

VS for Aqueous Acidimetry

A

HCL & H2SO4

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11
Q

PRIMARY STANDARD for Aqueous Acidimetry

A

SODIUM CARBONATE

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12
Q

SECONDARY STANDARD for Aqueous Acidimetry

A

SODIUM HYDROXIDE

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13
Q

DIRECT for Aqueous Acidimetry

A

NaOH, NaHCO3, Na Salicylate

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14
Q

RESIDUAL for Aqueous Acidimetry

A

NH4Cl, METHENAMINE, ZnO, POTASSIUM SODIUM TARTRATE, TARTRATE

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15
Q

VS for Non- Aqueous Acidimetry

A

Perchloric acid in glacial acetic acid & Perchloric acid, HBr

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16
Q

PRIMARY STANDARD AND SECONDARY STANDARD for Non- Aqueous Acidimetry

A

POTASSIUM BIPHTHALATE

17
Q

DIRECT/RESIDUAL for Non- Aqueous Acidimetry

A

METHACOLINE CL

18
Q

mEq of Na2CO3

A

0.053

19
Q

mEq of ZnO

A

0.037

20
Q

mEq of SODIUM BORATE H3BO3

A

0.1907

21
Q

A method designed to determine and quantify
ammonia in ammonium sulfate obtained by
decomposing organic substance with sulfuric acid

A

KJELDAHL Method
Nitrogen determination

22
Q

serve as
catalysts FOR KJELDAHL METHOD

A

K2SO4, anhy Na2SO4, CuSO4, Se

23
Q

if N is as NO3, ______ is added

A

salicylic acid

24
Q

Phases in Kjeldahl Method

A

1.In order to convert the amine nitrogen in the sample to
ammonium ions, it is first digested in powerful sulfuric acid with
the assistance of a catalyst.
2.After being heated and distilled, the ammonium ions are
changed into ammonia gas. The ammonia gas is introduced into a
solution for trapping where it dissolves and reverts to an
ammonium ion,
3.Finally, a computation is conducted after titrating with a
standard solution to establish how much ammonia has been
trapped.

25
Q

Advantages of Kjeldahl
Method

A

1.The Kjeldahl method continues to be the
gold standard for comparison with all other
procedures and is widely applied
internationally.
2.It has become a key method for estimating
the amount of protein in foods due to its
universality, high precision, and good
reproducibility

26
Q

Limitations of Kjeldahl
Method

A

Kjeldahl method is not appropriate for
compounds with nitrogen in azo and nitro
groups or in rings (quinoline, pyridine, etc.)
because the Kjeldahl process cannot be
used in these situations to turn the
nitrogen into ammonium sulphate.

27
Q

The total nitrogen present in organic substances
is widely renowned as

A

total Kjeldahl nitrogen

28
Q

It is majorly utilized in sewage treatment plants,
treat ment of industrial effluent as it is considered
as an useful tool in the chemical analysis of soil
water or wastewater.

A

Total Kjeldahl Nitrogen

29
Q

This method is well accepted globally for its
accuracy, versatility and efficient strategy.

A

Total Kjeldahl Nitrogen