ACIDIMETRY Flashcards
Is the analysis of a base using an
accurately measured volume of standard acid
solution
Acidimetry
if using an accurately measured volume of a standard acid solution
DIRECT
If the process requires adding an excess
of the standard acid solution and determining the
amount in excess by residual titration with
standard alkali solution
RESIDUAL
What kind of assay is Assay of Sodium Bicarbonate
DIRECT ACIDIMETRIC ASSAY
Assay of Sodium Bicarbonate
- 3 g of NaHCO3 dissolved in 25 ml of water
- Add the indicator
- Titrate with 1 N Sulfuric
acid
mEq of NaHCO3
0.084
What kind of assay is Assay of Zinc Oxide
RESIDUAL ACIDIMETRIC ASSAY
Assay of Zinc Oxide
- accurately weighed sample of zinc oxide
- add ammonium chloride
- dissolved in 50 mL of 1-N sulfuric acid
- Indicator is added
- excess acid is titrated with sodium hydroxide until the endpoint is reached.
- Calculate the
percentage
purity of zinc
oxide.
mEq of ZnO
0.0407
VS for Aqueous Acidimetry
HCL & H2SO4
PRIMARY STANDARD for Aqueous Acidimetry
SODIUM CARBONATE
SECONDARY STANDARD for Aqueous Acidimetry
SODIUM HYDROXIDE
DIRECT for Aqueous Acidimetry
NaOH, NaHCO3, Na Salicylate
RESIDUAL for Aqueous Acidimetry
NH4Cl, METHENAMINE, ZnO, POTASSIUM SODIUM TARTRATE, TARTRATE
VS for Non- Aqueous Acidimetry
Perchloric acid in glacial acetic acid & Perchloric acid, HBr