Alcohols, Phenols and Thiols Flashcards

1
Q

An alcohol is an organic compound in which an ___________ is bonded to a saturated carbon atom.

A

—OH group

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2
Q

A saturated carbon atom is a carbon atom that is bonded to how many other atoms

A

four

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3
Q

The —OH group, the functional group that is characteristic of an alcohol, is called a __________

A

hydroxyl group

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4
Q

2 types of naming alcohol,

A

(1) common name

(2) IUPAC name

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5
Q

in naming alcohols that contain a single hydroxyl group, the chain name is obtained by dropping the final -e from the alkane name and adding the suffix _______

A

-ol

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6
Q

these are the alcohols that possess more than one hydroxyl group

A

polyhydroxy alcohols

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7
Q

An alcohol in which two hydroxyl groups are present is named as a ______

A

diol

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8
Q

alcohols containing three hydroxyl groups is named as a ______, and so on.

A

triol

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9
Q

3 commonly encountered monohydroxy alcohols

A

methyl alcohol
ethyl alcohol
isopropyl alcohol

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10
Q

2 commonly encountered diols

A

propylene glycol

ethylene glycol

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11
Q

commonly encountered triol

A

glycerine (glycerol)

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12
Q

it is an alcohol with one carbon atom and one —OH group, and is the simplest alcohol.

A

methyl alcohol

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13
Q

an alcohol where fires are easier to put out than gasoline fires because water mixes with and dilutes with it.

A

methyl alcohol

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14
Q

an alcohol that has excellent solvent properties, and it is the solvent of choice for paints, shellacs, and varnishes

A

methyl alcohol

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15
Q

Methyl alcohol is sometimes called _____________, terminology that draws attention to an early method for its preparation—the heating of wood to a high temperature in the absence of air.

A

wood alcohol

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16
Q

Drinking methyl alcohol is __________.

A

very dangerous

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17
Q

Within the human body, methyl alcohol is oxidized by the liver enzyme alcohol dehydrogenase to the toxic metabolites _________ and __________.

A

formaldehyde and formic acid

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18
Q

Formaldehyde can cause __________ (temporary or permanent).

A

blindness

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19
Q

___________ causes acidosis

A

Formic acid

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20
Q

it is the two-carbon monohydroxy alcohol

A

ethyl alcohol

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21
Q

the alcohol present in alcoholic beverages and is commonly referred to simply as alcohol or drinking alcohol.

A

ethyl alcohol

22
Q

__________, the first oxidation product, is largely responsible for the symptoms of ____________.

A

Acetaldehyde; hangover

23
Q

Ethyl alcohol oxidation products are _________ than those of methyl alcohol

A

less toxic

24
Q

Long-term excessive use of ethyl alcohol may cause undesirable effects such as ____________, __________, ___________.

A

cirrhosis of the liver, loss of memory, and strong physiological addiction

25
Links have also been established between certain birth defects and the ingestion of ethyl alcohol by women during pregnancy ________________.
fetal alcohol syndrome
26
Ethyl alcohol can be produced by _______________________ found in plant extracts
yeast fermentation of sugars
27
The synthesis of ethyl alcohol in this manner, from grains such as corn, rice, and barley, is the reason why ethyl alcohol is often called ________________.
grain alcohol
28
______________ is ethyl alcohol that has been rendered unfit to drink by the addition of small amounts of toxic substances
Denatured alcohol
29
Almost all of the ethyl alcohol used for ____________ is denatured alcohol.
industrial purposes
30
volume percent of ethyl alcohol present in beer
3.2-9%
31
volume percent of ethyl alcohol present in scope (mouth wash)
18%
32
volume percent of ethyl alcohol present in nyquil
25%
33
volume percent of ethyl alcohol present in almond extract
50%
34
volume percent of ethyl alcohol present in vicks 44
10%
35
volume percent of ethyl alcohol present in wine (unfortified)
12%
36
volume percent of ethyl alcohol present in brandy
40-45%
37
volume percent of ethyl alcohol present in whiskey
45-55%
38
volume percent of ethyl alcohol present in rum
45%
39
volume percent of ethyl alcohol present in vanilla extract
35%
40
volume percent of ethyl alcohol present in colgate
17%
41
A 70% isopropyl alcohol–30% water solution is marketed as _______
rubbing alcohol
42
Isopropyl alcohol’s rapid evaporation rate creates a ______________ when it is applied to the skin, hence its use for alcohol rubs to combat high body temperature.
dramatic cooling effect
43
Isopropyl alcohol has a ______ taste.
bitter
44
Its toxicity is ________ that of ethyl alcohol, but it causes few fatalities because it often induces vomiting and thus doesn’t stay down long enough to be fatal
twice
45
Large amounts (about 150 mL) of ingested isopropyl alcohol can be fatal; death occurs from paralysis of the ______________
central nervous system
46
what is the IUPAC name for ethylene glycol
1,2-Ethanediol
47
IUPAC name for propylene glycol
1,2-propanediol
48
_____________ and ___________are the two simplest alcohols possessing two —OH groups.
Ethylene glycol and propylene glycol
49
A ________ is a diol in which the two —OH groups are on adjacent carbon atoms.
glycol
50
Both of these alcohols are colorless, odorless, high-boiling liquids that are completely miscible with water.
propylene and ethylene alcohol