acid/base and Redox Flashcards
cations and anions
cations- loose an electon becomes positive
anions- gains an electron and becomes negative
define acids
hydrogen ion donor
produce hydrogen ions
bronsted-lowry theory of acids and bases
an acid is a proton donor
a base is a proton acceptor
arrhenius theory of acids and bases
acids produce hydrogen ions in solution
bases produce hydroxide ions in solution
lewis theory of acids and bases
an acid is an electron pair acceptor
a base is an electron pair donor
base definition
hydrogen ion acceptor
compound that can undergo chemical change to combine with a hydrogen ion
what is omitted when considering acids in aqueous solution
water
conjugate acid-base
acid and base operate as a pair
acid donates a hydrogen to the base
acids and bases cannot operate in isolation
an acid must have a base to which donates a hydrogen ion
what is the general equation for acid-base reaction?
HA + B - A- + BH+
acid- base balance
acids and bases that ionise completely = strong
acids and bases dissociate incompletely =weak
bicarbonate system
The body usually buffers weaker organic acids like lactic acid
the addition of H+ ions drives reaction to right= more carbonic acid which consumes bicarbonate
if H+ ions fall carbonic acid dissociates generating H+ ions
20:1 ratio of bicarbonte : carbonic acid
PH
measure of concentration of hydronium ions in a solution
PH is the negative logarithm of the hydrogen ion concentration
PH = log10 1/(H+) = -log10(H+)
the hydronium ion concentraion can be found from the pH by the reverse of the mathematical operation employed to find the pH
inverse the log (-PH)
what is a strong acid?
it is an acids readiness to donate a hydrogen ion vise versa for a weak acid
Ka and pKa
Ka =(H3O+)(A-)/(HA)
pKa = -log(Ka)
strong acid has a large Ka
weak acid has a small Ka
oxidation and reduction
oxidation- is the loss of electrons = increase in oxidation state
reduction - is the gain of elections = decrease in oxidation state
oxidised and reduced
oxidised- when a chemical species loses or donates electrons it undergoes oxidation
when a chemical species gains electrons or accepts electrons it undergoes reduction
redox
process of oxidation and reduction - transfer of electrons from one atom to another= complementary process= occurs simultaneously
electrons can be physically transferred from one species to another