acid/base and Redox Flashcards

1
Q

cations and anions

A

cations- loose an electon becomes positive
anions- gains an electron and becomes negative

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2
Q

define acids

A

hydrogen ion donor
produce hydrogen ions

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3
Q

bronsted-lowry theory of acids and bases

A

an acid is a proton donor
a base is a proton acceptor

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4
Q

arrhenius theory of acids and bases

A

acids produce hydrogen ions in solution
bases produce hydroxide ions in solution

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5
Q

lewis theory of acids and bases

A

an acid is an electron pair acceptor
a base is an electron pair donor

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6
Q

base definition

A

hydrogen ion acceptor
compound that can undergo chemical change to combine with a hydrogen ion

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7
Q

what is omitted when considering acids in aqueous solution

A

water

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8
Q

conjugate acid-base

A

acid and base operate as a pair
acid donates a hydrogen to the base
acids and bases cannot operate in isolation
an acid must have a base to which donates a hydrogen ion

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9
Q

what is the general equation for acid-base reaction?

A

HA + B - A- + BH+

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10
Q

acid- base balance

A

acids and bases that ionise completely = strong
acids and bases dissociate incompletely =weak

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11
Q

bicarbonate system

A

The body usually buffers weaker organic acids like lactic acid
the addition of H+ ions drives reaction to right= more carbonic acid which consumes bicarbonate
if H+ ions fall carbonic acid dissociates generating H+ ions
20:1 ratio of bicarbonte : carbonic acid

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12
Q

PH

A

measure of concentration of hydronium ions in a solution
PH is the negative logarithm of the hydrogen ion concentration

PH = log10 1/(H+) = -log10(H+)
the hydronium ion concentraion can be found from the pH by the reverse of the mathematical operation employed to find the pH

inverse the log (-PH)

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13
Q

what is a strong acid?

A

it is an acids readiness to donate a hydrogen ion vise versa for a weak acid

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14
Q

Ka and pKa

A

Ka =(H3O+)(A-)/(HA)
pKa = -log(Ka)
strong acid has a large Ka
weak acid has a small Ka

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15
Q

oxidation and reduction

A

oxidation- is the loss of electrons = increase in oxidation state
reduction - is the gain of elections = decrease in oxidation state

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16
Q

oxidised and reduced

A

oxidised- when a chemical species loses or donates electrons it undergoes oxidation
when a chemical species gains electrons or accepts electrons it undergoes reduction

17
Q

redox

A

process of oxidation and reduction - transfer of electrons from one atom to another= complementary process= occurs simultaneously
electrons can be physically transferred from one species to another